The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
This thesis describes the results from two different projects in organosulfur chemistry, the first p...
The radical cations of a series of aryl benzyl sulfoxides (4-X-C6H4CH2SOC6H4Y+•) have been generated...
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction wa...
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction wa...
A new strategy for the activation of aryl sulfones towards homolytic and heterolytic cleavage via in...
Reductive cleavage of alkyl phenyl sulfones follows a pathway which can involve fission of either th...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
Ab initio and density functional theory (DFT) calculations predict that intramolecular homolytic sub...
A comprehensive mechanistic investigation was conducted on the coupling reaction of aryl sulfoxides ...
Ab initio and density functional theory (DFT) calculations predict that intramolecular homolytic sub...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
Rearrangements of 1,3-oxathiolane sulfoxides 8 and 9 in the presence of base are described from a me...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
This thesis describes the results from two different projects in organosulfur chemistry, the first p...
The radical cations of a series of aryl benzyl sulfoxides (4-X-C6H4CH2SOC6H4Y+•) have been generated...
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction wa...
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction wa...
A new strategy for the activation of aryl sulfones towards homolytic and heterolytic cleavage via in...
Reductive cleavage of alkyl phenyl sulfones follows a pathway which can involve fission of either th...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
Ab initio and density functional theory (DFT) calculations predict that intramolecular homolytic sub...
A comprehensive mechanistic investigation was conducted on the coupling reaction of aryl sulfoxides ...
Ab initio and density functional theory (DFT) calculations predict that intramolecular homolytic sub...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
Rearrangements of 1,3-oxathiolane sulfoxides 8 and 9 in the presence of base are described from a me...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via init...
This thesis describes the results from two different projects in organosulfur chemistry, the first p...
The radical cations of a series of aryl benzyl sulfoxides (4-X-C6H4CH2SOC6H4Y+•) have been generated...