Pentafluorophenylimido Alkylidene Complexes of Molybdenum and Tungsten
- Jian Yuan (585683)
- Richard R. Schrock (1295601)
- Peter Müller (1295607)
- Jonathan C. Axtell (1611628)
- Graham E. Dobereiner (1920565)
DOIAbstract
Pentafluorophenylimido alkylidene complexes of molybdenum and tungsten have been prepared in good yields. Examples include Mo(NC<sub>6</sub>F<sub>5</sub>)(CHCMe<sub>2</sub>Ph)(Me<sub>2</sub>Pyr)<sub>2</sub> (Me<sub>2</sub>Pyr = 2,5-dimethylpyrrolide), W(NC<sub>6</sub>F<sub>5</sub>)(CH-t-Bu)(DME)(Pyrrolide)<sub>2</sub>, Mo(NC<sub>6</sub>F<sub>5</sub>)(CHCMe<sub>2</sub>Ph)[OC(CF<sub>3</sub>)<sub>3</sub>]<sub>2</sub>, W(NC<sub>6</sub>F<sub>5</sub>)(CH-t-Bu)(DME)[OC(CF<sub>3</sub>)<sub>3</sub>]<sub>2</sub>, Mo(NC<sub>6</sub>F<sub>5</sub>)(CHCMe<sub>2</sub>Ph)[OC(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]<sub>2</sub>, W(NC<sub>6</sub>F<sub>5</sub>)(CH-t-Bu)[OC(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]<sub>2</sub>, Mo(NC<sub...
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