Hydrogel Particles as a Particulate Stabilizer for Dispersion Polymerization

Hydrogel particles composed of poly­(<i>N</i>-isopropylacrylamide) were used as a particulate steric stabilizer for the dispersion polymerization of styrene for the first time. The effects of the size and concentration of the hydrogel particles on the resultant polystyrene particles were investigated. As expected, the hydrogel particles indeed play the role of steric stabilizer for dispersion polymerization. Moreover, some of the resultant polystyrene particles were covered with hydrogel particles, which was confirmed by electron microscopy and X-ray photoelectron spectroscopy