We recently reported the formation of a bridging carbonate complex [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ–η<sup>1</sup>:κ<sup>2</sup>-CO<sub>3</sub>)] via reductive cleavage of CO<sub>2</sub>, yielding a μ-oxo bridged complex, followed by the insertion of another molecule of CO<sub>2</sub>. In a similar strategy, we were able to isolate and characterize a series of mixed carbonate complexes U–CO<sub>2</sub>E–U, U–CS<sub>2</sub>E–U, and even U–OC(S)Se–U, by reacting bridged chalcogenide complexes [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ-E)] (E = S, Se) with CO<sub>2</sub>, CS<sub>2</sub>, and COS. These chalcogenido mixed-carbonate complexes represent the first of their kind
The selectivity of the mixed-sandwich U(III) complexes of the type [U(η-C8H6{SiiR3-1,4} 2)(η-CpR′)] ...
The stoichiometric reaction of 1 equiv of CO with [(U(eta-C8H6{SiiPr3-1,4}2)(eta-Cp*)] affords the l...
Three novel unsymmetrical η<sup>3</sup>-2-azaallyl cobalt(I) complexes, [(2-PPh<sub>2</sub>)C<sub>...
We recently reported the formation of a bridging carbonate complex [{((<sup>Ad</sup>ArO)<sub>3</sub>...
The uranium(IV)/uranium(IV) μ-sulfide complex [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ...
The synthesis and molecular structures of a range of uranium(III) mixed sandwich complexes of the ty...
The mixed-sandwich U(III) complexes [U(eta-(C8H6SiPr3)-Pr-i-1,4}(2))(eta-Cp-R)(THF)] (R = Me-5, Me4H...
International audienceThe synthesis and molecular structures of a range of uranium(III) mixed sandwi...
The new dianionic ligand C<sub>6</sub>H<sub>4</sub>{<i>p</i>-C(CH<sub>3</sub>)<sub>2</sub>C<sub>6</...
A series of six binuclear Co(II)–thiolate complexes, [Co2(BPMP)(S–C6H4-o-X)2]1+ (X = OMe, 2; NH2, 3)...
The selective insertion of CO and CO<sub>2</sub> into the C–O and O–H bonds of alcohols by the Se–Ru...
The stoichiometric reaction of 1 equiv of CO with [(U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)] affords the linea...
The U(III) mixed-sandwich compound [U(¿-C5Me4H)(¿-C8H6{SiiPr3-1,4}2)(THF)] 1 may be prepared by sequ...
Calculations reveal a multistep pathway towards formation of linear [U](2)-(mu-eta(1):eta(1)-C2O2); ...
The U(III) mixed-sandwich compound [U(eta-C5Me4H)(eta-C8H6{SiiPr3-1,4}2)(THF)] 1 may be prepared by ...
The selectivity of the mixed-sandwich U(III) complexes of the type [U(η-C8H6{SiiR3-1,4} 2)(η-CpR′)] ...
The stoichiometric reaction of 1 equiv of CO with [(U(eta-C8H6{SiiPr3-1,4}2)(eta-Cp*)] affords the l...
Three novel unsymmetrical η<sup>3</sup>-2-azaallyl cobalt(I) complexes, [(2-PPh<sub>2</sub>)C<sub>...
We recently reported the formation of a bridging carbonate complex [{((<sup>Ad</sup>ArO)<sub>3</sub>...
The uranium(IV)/uranium(IV) μ-sulfide complex [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ...
The synthesis and molecular structures of a range of uranium(III) mixed sandwich complexes of the ty...
The mixed-sandwich U(III) complexes [U(eta-(C8H6SiPr3)-Pr-i-1,4}(2))(eta-Cp-R)(THF)] (R = Me-5, Me4H...
International audienceThe synthesis and molecular structures of a range of uranium(III) mixed sandwi...
The new dianionic ligand C<sub>6</sub>H<sub>4</sub>{<i>p</i>-C(CH<sub>3</sub>)<sub>2</sub>C<sub>6</...
A series of six binuclear Co(II)–thiolate complexes, [Co2(BPMP)(S–C6H4-o-X)2]1+ (X = OMe, 2; NH2, 3)...
The selective insertion of CO and CO<sub>2</sub> into the C–O and O–H bonds of alcohols by the Se–Ru...
The stoichiometric reaction of 1 equiv of CO with [(U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)] affords the linea...
The U(III) mixed-sandwich compound [U(¿-C5Me4H)(¿-C8H6{SiiPr3-1,4}2)(THF)] 1 may be prepared by sequ...
Calculations reveal a multistep pathway towards formation of linear [U](2)-(mu-eta(1):eta(1)-C2O2); ...
The U(III) mixed-sandwich compound [U(eta-C5Me4H)(eta-C8H6{SiiPr3-1,4}2)(THF)] 1 may be prepared by ...
The selectivity of the mixed-sandwich U(III) complexes of the type [U(η-C8H6{SiiR3-1,4} 2)(η-CpR′)] ...
The stoichiometric reaction of 1 equiv of CO with [(U(eta-C8H6{SiiPr3-1,4}2)(eta-Cp*)] affords the l...
Three novel unsymmetrical η<sup>3</sup>-2-azaallyl cobalt(I) complexes, [(2-PPh<sub>2</sub>)C<sub>...