New superbases, those organic compounds whose basicities are greater than that of proton sponge, are suggested that involve extended hydrogen-bonding networks. Addition of aminoethyl and related groups to the 1,8-diaminonaphthalene framework provide second- and third-layer hydrogen bonding in the conjugate base. DFT computations predict these compounds to be 10–15 kcal mol<sup>–1</sup> more basic than the proton sponge
A very short-strong hydrogen bond (<2 Å, >20kcal/mol) is found in the monoanion of certain dicarboxy...
New neutral organic superbases with 1- azaazulene(s) as a molecular backbone are computationally des...
The experimental pK(HB) hydrogen-bond (HB) basicity scale and the corresponding Delta H-HB(circle mi...
Extended hydrogen-bonding networks as a mechanism for creating superbases is explored through six di...
Extended hydrogen bond networks can substantially increase basicity through stabilization of the res...
ABSTRACT: Hydrogen bonding plays an important role in the interaction of biological molecules and th...
Certain aromatic diamines (the “proton sponges”) are found to have exceptionally high basicity const...
DFT calculations revealed that 1, 8-diazanaphthalene di-N-oxides provide extraordinary oxygen superb...
Nine new molecular complexes of the proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) with subs...
A very short-strong hydrogen bond (, >20kcal/mol) is found in the monoanion of certain dicarboxylic ...
B3LYP/aug-cc-pVDZ computations were carried out on polyamines with up to seven amino groups. The gas...
Utilizing several different trialkylarsine oxides and substituted pyridine N-oxides as a hydrogen bo...
2,4-Diamino-1,3,5-triazinyl (DAT) groups are known to form N–H···N hydrogen bonds according to relia...
The density functional theory (DFT) calculations were performed for a series of new molecular framew...
Hydrogen bonding plays an essential part in dictating the properties of natural and synthetic materi...
A very short-strong hydrogen bond (<2 Å, >20kcal/mol) is found in the monoanion of certain dicarboxy...
New neutral organic superbases with 1- azaazulene(s) as a molecular backbone are computationally des...
The experimental pK(HB) hydrogen-bond (HB) basicity scale and the corresponding Delta H-HB(circle mi...
Extended hydrogen-bonding networks as a mechanism for creating superbases is explored through six di...
Extended hydrogen bond networks can substantially increase basicity through stabilization of the res...
ABSTRACT: Hydrogen bonding plays an important role in the interaction of biological molecules and th...
Certain aromatic diamines (the “proton sponges”) are found to have exceptionally high basicity const...
DFT calculations revealed that 1, 8-diazanaphthalene di-N-oxides provide extraordinary oxygen superb...
Nine new molecular complexes of the proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) with subs...
A very short-strong hydrogen bond (, >20kcal/mol) is found in the monoanion of certain dicarboxylic ...
B3LYP/aug-cc-pVDZ computations were carried out on polyamines with up to seven amino groups. The gas...
Utilizing several different trialkylarsine oxides and substituted pyridine N-oxides as a hydrogen bo...
2,4-Diamino-1,3,5-triazinyl (DAT) groups are known to form N–H···N hydrogen bonds according to relia...
The density functional theory (DFT) calculations were performed for a series of new molecular framew...
Hydrogen bonding plays an essential part in dictating the properties of natural and synthetic materi...
A very short-strong hydrogen bond (<2 Å, >20kcal/mol) is found in the monoanion of certain dicarboxy...
New neutral organic superbases with 1- azaazulene(s) as a molecular backbone are computationally des...
The experimental pK(HB) hydrogen-bond (HB) basicity scale and the corresponding Delta H-HB(circle mi...
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