Catalytic Hydrotrifluoromethylation of Unactivated Alkenes
- Satoshi Mizuta (1951063)
- Stefan Verhoog (1980925)
- Keary M. Engle (1606045)
- Tanatorn Khotavivattana (1990240)
- Miriam O’Duill (1667278)
- Katherine Wheelhouse (1980922)
- Gerasimos Rassias (1980919)
- Maurice Médebielle (1980916)
- Véronique Gouverneur (1300443)
Publication date
February 2013
DOIAbstract
A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF<sub>3</sub> source and MeOH as the reductant is disclosed. This effective transformation operates at room temperature in the presence of 5 mol % Ru(bpy)<sub>3</sub>Cl<sub>2</sub>; the process is characterized by its operational simplicity and functional group tolerance
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