A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts

Yoshio Hato (1947379)
Yoshihiro Oonishi (1989148)
Yasunori Yamamoto (34512)
Kiyohiko Nakajima (1392283)
Yoshihiro Sato (1490716)

August 2016

Stereoselective construction of spiro-fused tricyclic compounds from enynes having a tethered imine ...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Arianne C. Hunter (4855900)
Steven C. Schlitzer (4855906)
Joseph C. Stevens (4855903)
Bilal Almutwalli (4855897)
Indrajeet Sharma (1312404)

January 2018

A convergent approach for the stereoselective synthesis of diverse spiroethers is described. The rea...

A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Arianne C. Hunter (4855900)
Steven C. Schlitzer (4855906)
Joseph C. Stevens (4855903)
Bilal Almutwalli (4855897)
Indrajeet Sharma (1312404)

January 2018

A convergent approach for the stereoselective synthesis of diverse spiroethers is described. The rea...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Stereoselective Spirocyclizations Initiated by Metal Carbenes

Hunter, Arianne

March 2019

Within the field of drug design, there is a great interest in the development of synthetic libraries...

Relay Catalysis of Rh (II) and Cobaloxime: Stereoselective Synthesis of Spiroindanones from N‑Sulfonyl-1,2,3-triazoles

Zhao Liu (582169)
Qiuchen Du (1789314)
Hongbin Zhai (1457509)
Yun Li (692280)

November 2018

A novel relay Rh (II)/cobaloxime (III) dual catalysis strategy has been developed for the stereosele...

Cascade Reactions to Access Bioactive Scaffolds

Schlitzer, Steven

July 2020

In the recent decade there has been a shift in drug development to favor planar, aromatic small mole...

Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes

Muthusamy, S
Gunanathan, C
Nethaji, M

March 2004

The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to int...

Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes

Muthusamy, S
Gunanathan, C
Nethaji, M

March 2004

The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to int...

Diversity-oriented approach to spirocycles via ring-closing metathesis

KOTHA, S
ALI, R
CHINNAM, AK

January 2014

We have demonstrated a simple and an efficient method for the synthesis of spirocycles starting with...

Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts

Yoshio Hato (1947379)
Yoshihiro Oonishi (1989148)
Yasunori Yamamoto (34512)
Kiyohiko Nakajima (1392283)
Yoshihiro Sato (1490716)

August 2016

Stereoselective construction of spiro-fused tricyclic compounds from enynes having a tethered imine ...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Arianne C. Hunter (4855900)
Steven C. Schlitzer (4855906)
Joseph C. Stevens (4855903)
Bilal Almutwalli (4855897)
Indrajeet Sharma (1312404)

January 2018

A convergent approach for the stereoselective synthesis of diverse spiroethers is described. The rea...

A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Arianne C. Hunter (4855900)
Steven C. Schlitzer (4855906)
Joseph C. Stevens (4855903)
Bilal Almutwalli (4855897)
Indrajeet Sharma (1312404)

January 2018

A convergent approach for the stereoselective synthesis of diverse spiroethers is described. The rea...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Diastereoselective Access to Polyoxygenated Polycyclic Spirolactones through a Rhodium-Catalyzed [3+2] Cycloaddition Reaction: Experimental and Theoretical Studies

Rodier, Fabien
Parrain, Jean-Luc
Chouraqui, Gaëlle
Commeiras, Laurent

January 2013

International audienceThe synthetic utility of γ-alkylidenebutenolides is demonstrated as highly com...

Stereoselective Spirocyclizations Initiated by Metal Carbenes

Hunter, Arianne

March 2019

Within the field of drug design, there is a great interest in the development of synthetic libraries...

Relay Catalysis of Rh (II) and Cobaloxime: Stereoselective Synthesis of Spiroindanones from N‑Sulfonyl-1,2,3-triazoles

Zhao Liu (582169)
Qiuchen Du (1789314)
Hongbin Zhai (1457509)
Yun Li (692280)

November 2018

A novel relay Rh (II)/cobaloxime (III) dual catalysis strategy has been developed for the stereosele...

Cascade Reactions to Access Bioactive Scaffolds

Schlitzer, Steven

July 2020

In the recent decade there has been a shift in drug development to favor planar, aromatic small mole...

Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes

Muthusamy, S
Gunanathan, C
Nethaji, M

March 2004

The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to int...

Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes

Muthusamy, S
Gunanathan, C
Nethaji, M

March 2004

The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to int...

Diversity-oriented approach to spirocycles via ring-closing metathesis

KOTHA, S
ALI, R
CHINNAM, AK

January 2014

We have demonstrated a simple and an efficient method for the synthesis of spirocycles starting with...

Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts

Yoshio Hato (1947379)
Yoshihiro Oonishi (1989148)
Yasunori Yamamoto (34512)
Kiyohiko Nakajima (1392283)
Yoshihiro Sato (1490716)

August 2016

Stereoselective construction of spiro-fused tricyclic compounds from enynes having a tethered imine ...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes

Bingxian Liu (2038690)
Panjie Hu (3902923)
Ying Zhang (1235337)
Yunyun Li (1433416)
Dachang Bai (3902926)
Xingwei Li (1391965)

September 2017

Rh(III)-catalyzed [3 + 2] annulation of cyclic N-sulfonyl or N-acyl ketimines with ac...

A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Abstract

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A Convergent Approach to Diverse Spiroethers through Stereoselective Trapping of Rhodium Carbenoids with Gold-Activated Alkynols

Abstract

Extracted data

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