The oxygen isotope composition of Karoo and Etendeka picrites: High δ18O mantle or crustal contamination?

Olivine and orthopyroxene phenocrysts from picrite and picrate basalt lavas and dykes (Mg# 64-80) from the Tuli and Mwanezi (Nuanetsi) regions of the ~180 Ma Karoo Large Igneous province (LIP) have δ18O values that range from 6.0 to 6.7 ‰ (Fig. 1), suggesting that they crystallized from magmas having δ18O values about 1 to 1.5 ‰ higher than expected in an entirely mantle-derived magma. Olivines from picrite and picrite basalt dykes from the 135 Ma Etendeka LIP of Namibia and Karoo-age picrite dykes from Dronning Maud Land, Antarctica do not have such elevated δ18O values. The Etendeka picrites show good correlations between δ18O value and Sr-, Nd- and Pb-isotope ratios that are consistent with previously proposed models of crustal contamination (e.g. Thompson et al., 2007). Explanations for the high δ18O values in Tuli/Mwenezi picrites are limited to (i) alteration, (ii) crustal contamination, and (iii) derivation from mantle with an abnormally high δ18O. The lack of variation in olivine and orthopyroxene δ18O values, together with the lack of correlation between mineral and whole-rock δ18O values are not consistent with alteration being the cause of high δ18O values. The high δ18O values in selected olivine cores have been confirmed by SIMS, and aggressive cleaning of crystals with HF makes no difference to the δ18O value obtained. Average εNd and εSr values of -8 and +16, and high concentrations of incompatible elements such as K are typical of picrites from the Mwanezi (Nuanetsi) region, which have been explained by a variety of models that range from crustal contamination to derivation from the ‘enriched’ mantle lithosphere. The primitive character of the magmas combined with the lack of correlation between δ18O values and radiogenic isotope composition and MgO content or Mg# are inconsistent with crustal contamination, and lend weight to arguments in favour of an 18O-enriched mantle source having high incompatible trace element concentration and enriched radiogenic isotope composition. Although elevated initial Sr isotope ratios, εNd values of -8, and δ18O values about 1 ‰ higher than expected for mantle-derived magma are also a feature of the Bushveld mafic and ultramafic magmas, it is unlikely that a long-lived 18O-enriched mantle source would have survived for nearly 2 Ga. Incorporation of crustal material into the mantle by subduction or delamination of the lower crust are the most likely mechanisms for enriching the mantle in 18O