Influence of particle size and tunable interactions on isotropic-nematic transition of block copolymer single crystal platelet suspensions

We have studied the influence of the particle size and the tunable lateral interactions on the isotropic-nematic (I-N) phase transition of a plate-like colloidal system. The particles are single crystals of a block copolymer PS-b-PLLA (BCSC) prepared using a self-seeding procedure. These lozenge shape crystals have a uniform thickness and a narrowly distributed lateral size. The equilibrium phase behavior and I-N phase transition have been characterized using crossed polarizers at the room temperature. A nematic phase exists for all systems with size ranging from 700 to 4000 nm. For smaller crystals (<1200 nm), the I-N phase transition follows a process of slow sedimentation and subsequent macroscopic phase separation, resulting in a highly oriented nematic phase with a sharp I-N interface. For larger crystals (>= 1200 nm), the I-N phase transition follows a process of nucleation and subsequent sedimentation, resulting in a random orientation of crystals in the nematic phase and a rough I-N interface. The I-N transition occurs at a very low volume fraction (