Homopolymerization of butadiene has been carried out with a new series of binary catalyst system Nd(OR)3-nCln-AlEt3 and the catalytic activity as well as the microstructure of the resulting polymer have been studied. The results indicate that the stereospecificity of the polybutadiene obtained with these binary catalyst system(when n=2) is similar to that prepared with ternary system Nd(OR)3-Al2Et3Cl3-AlEt3,y..
The tritiated alcohol quench method has been used for determining the number of active centers in th...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
Living characteristics of facilely prepared Ziegler-Natta type catalyst system consisting of iron(II...
With a new series of binary catalyst Nd(OR)3-nCln-AlEt3 prepared in our laboratory, the effect of ca...
Nowadays the catalyst systems based on neodymium are the ones most used in the high cis polybutadien...
The present work describes the stereospecific polymerization of 1,3-butadiene catalyzed by a nickel ...
Coordinative chain transfer polymerization (CCTP) of 1,3-butadiene was assessed by employing several...
Butadiene polymerization, in both a highly cis- and trans-specific manner, was achieved by using a C...
In a first step, 1,3-butadiene was selectively polymerized at 60°C in styrene as solvent using NdV3/...
Foi estudado um processo de polimerização de butadieno, em escala de laboratório, para obtenção de p...
International audienceNickel allyl complexes are catalysts for the 1,4-regioselective polymerization...
This paper reports on the study of five neodymium bromide complexes of general formula NdBr3·nL prep...
The polymerization of butadiene(Bd), isoprene(Ip) and styrene(St) has been examined using the six ca...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
The tritiated alcohol quench method has been used for determining the number of active centers in th...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
Living characteristics of facilely prepared Ziegler-Natta type catalyst system consisting of iron(II...
With a new series of binary catalyst Nd(OR)3-nCln-AlEt3 prepared in our laboratory, the effect of ca...
Nowadays the catalyst systems based on neodymium are the ones most used in the high cis polybutadien...
The present work describes the stereospecific polymerization of 1,3-butadiene catalyzed by a nickel ...
Coordinative chain transfer polymerization (CCTP) of 1,3-butadiene was assessed by employing several...
Butadiene polymerization, in both a highly cis- and trans-specific manner, was achieved by using a C...
In a first step, 1,3-butadiene was selectively polymerized at 60°C in styrene as solvent using NdV3/...
Foi estudado um processo de polimerização de butadieno, em escala de laboratório, para obtenção de p...
International audienceNickel allyl complexes are catalysts for the 1,4-regioselective polymerization...
This paper reports on the study of five neodymium bromide complexes of general formula NdBr3·nL prep...
The polymerization of butadiene(Bd), isoprene(Ip) and styrene(St) has been examined using the six ca...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
The tritiated alcohol quench method has been used for determining the number of active centers in th...
11 pagesInternational audienceThe combination of a neodymium borohydride, Nd(BH4)3(THF)3 (1) or Cp*N...
Living characteristics of facilely prepared Ziegler-Natta type catalyst system consisting of iron(II...