Add to ORKGThe compounds O(CH2CH2C5H4)(2)Ln(THF)(2) [Ln = Sm(1), Yb(2)] were synthesized by the reduction of O(CH2CH2C5H4)(2)LnCl with sodium metal in tetrahydrofuran (THF) at room temperature. Recrystallization of 2 from dimethoxyethane (DME) produced the single-crystal O(CH2CH2C5H4)(2)Yb(DME) (3) whose structure has been determined by an X-ray diffraction study. The crystals are orthorhombic, space group Pcab, with a = 14.168(4), b = 13.541(6), c = 19.314(8) Angstrom, Z = 8, D-calc. = 1.66 g cm(-3)
The dinuclear complexes of 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolone-4')-1,5-pen...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Treatment of C5H4CH2CH2OMe · Li(TMEDA) (TMEDA = N, N, N´, N´ tetramethylethylenediamine) with half a...
By the reaction of Cp3Ln (Cp = C5H5; Ln = Dy, Ho, Yb) with equimolar n-propyl alcohol in THF (tetrah...
By the one-pot reaction of lanthanide trichloride with 2 equivalents of sodium cyclopentadienyl and ...
The reaction of [(diphenylphosphino)cyclopentadienyl]thallium [Tl(C5H4PPh2)] with metallic europium ...
LnCl(3) reacted with C6H5CH2C5H4Na in THF (tetrahydrofuran) in the ratio 1.1 at room temperature for...
The crystal structure of Cp2Yb . (CH3COCHCOCF3) has been determined by single-crystal X-ray diffract...
Reaction of 3-(2-pyridylmethyl)indenyl lithium (1) with LnI(2)(THF)(2) (Ln = Sm, Yb) in THF produced...
Reaction of YbCl3 with 3 equimolar CpNa (Cp = cyclopentadienide) in THF, followed by treatment with ...
Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 w...
CommunicationInternational audienceReduction of bis(tri-tert-butylcyclopentadienyl)dysprosium(III) c...
<p>The reaction of <i>N,N′</i>-bis(2-hydroxybenzyl)-<i>N,N′</i>-bis(2-pyridylmethyl)-<i>R</i>-1,2-pr...
[Cp3Yb] reacts with HOR (Cp = C5H5; R = CH2CH=CH2, CH2CH2Me) in thf (thf = tetrahydrofuran)at room t...
Research devoted to synthesis of new classes of lanthanide and actinide complexes is reported. Co-co...
The dinuclear complexes of 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolone-4')-1,5-pen...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Treatment of C5H4CH2CH2OMe · Li(TMEDA) (TMEDA = N, N, N´, N´ tetramethylethylenediamine) with half a...
By the reaction of Cp3Ln (Cp = C5H5; Ln = Dy, Ho, Yb) with equimolar n-propyl alcohol in THF (tetrah...
By the one-pot reaction of lanthanide trichloride with 2 equivalents of sodium cyclopentadienyl and ...
The reaction of [(diphenylphosphino)cyclopentadienyl]thallium [Tl(C5H4PPh2)] with metallic europium ...
LnCl(3) reacted with C6H5CH2C5H4Na in THF (tetrahydrofuran) in the ratio 1.1 at room temperature for...
The crystal structure of Cp2Yb . (CH3COCHCOCF3) has been determined by single-crystal X-ray diffract...
Reaction of 3-(2-pyridylmethyl)indenyl lithium (1) with LnI(2)(THF)(2) (Ln = Sm, Yb) in THF produced...
Reaction of YbCl3 with 3 equimolar CpNa (Cp = cyclopentadienide) in THF, followed by treatment with ...
Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 w...
CommunicationInternational audienceReduction of bis(tri-tert-butylcyclopentadienyl)dysprosium(III) c...
<p>The reaction of <i>N,N′</i>-bis(2-hydroxybenzyl)-<i>N,N′</i>-bis(2-pyridylmethyl)-<i>R</i>-1,2-pr...
[Cp3Yb] reacts with HOR (Cp = C5H5; R = CH2CH=CH2, CH2CH2Me) in thf (thf = tetrahydrofuran)at room t...
Research devoted to synthesis of new classes of lanthanide and actinide complexes is reported. Co-co...
The dinuclear complexes of 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolone-4')-1,5-pen...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Treatment of C5H4CH2CH2OMe · Li(TMEDA) (TMEDA = N, N, N´, N´ tetramethylethylenediamine) with half a...