[NH4](4)H[(PMo8V4V2O42)-V-IV-O-V] . 24H(2)O has been hydrothermally synthesized from ammonium vanadate and sodium molybdate in aqueous solution by adding phosphorous acid, and its structure determined by single crystal X-ray analysis. The heteropoly molybdovanadophosphate anion is a bicapped 'pseudo-Keggin' polyanion, two vanadium atoms are distributed at two 'capping' metal atom positions and other four vanadium atoms randomly distributed at eight metal atom positions. (C) 1998 Elsevier Science Ltd. All rights reserved
A novel organic-inorganic hybrid vanadium arsenate [H3V3O26(AsO4)(4)(phen)(8)(H2O)(2)](.)2H(2)O 1 (p...
Aqueous molybdovanadates have been studied by V-51 NMR spectroscopy over a wide range of metalion co...
The first molybdovanadate cluster with a polyarylimido trimetal fragment, [V4Mo3O14(NAr)(3)(mu(2)-NA...
The determination of complexes formed in weakly acidic aqueous solutions containing pentavalent vana...
An unusual polyoxometalate [H2N(C2H4)(2)NH2](4)(H3O)[(PMO2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)].H2...
Müller A, Krickemeyer E, DILLINGER S, Bögge H, Stammler A. [AS4MO6V7O39(SO4)](4-) - A SPECIES WITH A...
The compound ((NH4)7[VvO4W10VIV2IVO36]·ca. 22H2O (1) has been synthesized from an aqueous ammonium a...
A new vanadyl oxalatophosphate compound, (C10H10N2)[(VO)(HPO4)]2(C2O4), was synthesized via the hydr...
A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO...
A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO...
Reaction of sodium molybdate (Na2MoO4.2H2O) and ammonium metavanadate (NH4VO3) with hydroxylamine hy...
A novel phosphovanadate layered structure intercalated by 4,4 -bipyridinium cations, (C10H10N2)[(VO...
A novel dimer-tungstovanadate, (H3O)(4)[VW12O40Na (H2O)(4)](2), was hydrothermally synthesized and s...
The title compound, (H(2)en)(3)H3O {MO8V4O36 (VO4) (VO)(2)} . 4H(2)O, was hydrothermally synthesized...
The title heteropoly blue, (Bu4N)(6)H-10 [(PMo11MoO40)-Mo-VI-O-V](4) . H2O has been photochemically ...
A novel organic-inorganic hybrid vanadium arsenate [H3V3O26(AsO4)(4)(phen)(8)(H2O)(2)](.)2H(2)O 1 (p...
Aqueous molybdovanadates have been studied by V-51 NMR spectroscopy over a wide range of metalion co...
The first molybdovanadate cluster with a polyarylimido trimetal fragment, [V4Mo3O14(NAr)(3)(mu(2)-NA...
The determination of complexes formed in weakly acidic aqueous solutions containing pentavalent vana...
An unusual polyoxometalate [H2N(C2H4)(2)NH2](4)(H3O)[(PMO2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)].H2...
Müller A, Krickemeyer E, DILLINGER S, Bögge H, Stammler A. [AS4MO6V7O39(SO4)](4-) - A SPECIES WITH A...
The compound ((NH4)7[VvO4W10VIV2IVO36]·ca. 22H2O (1) has been synthesized from an aqueous ammonium a...
A new vanadyl oxalatophosphate compound, (C10H10N2)[(VO)(HPO4)]2(C2O4), was synthesized via the hydr...
A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO...
A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO...
Reaction of sodium molybdate (Na2MoO4.2H2O) and ammonium metavanadate (NH4VO3) with hydroxylamine hy...
A novel phosphovanadate layered structure intercalated by 4,4 -bipyridinium cations, (C10H10N2)[(VO...
A novel dimer-tungstovanadate, (H3O)(4)[VW12O40Na (H2O)(4)](2), was hydrothermally synthesized and s...
The title compound, (H(2)en)(3)H3O {MO8V4O36 (VO4) (VO)(2)} . 4H(2)O, was hydrothermally synthesized...
The title heteropoly blue, (Bu4N)(6)H-10 [(PMo11MoO40)-Mo-VI-O-V](4) . H2O has been photochemically ...
A novel organic-inorganic hybrid vanadium arsenate [H3V3O26(AsO4)(4)(phen)(8)(H2O)(2)](.)2H(2)O 1 (p...
Aqueous molybdovanadates have been studied by V-51 NMR spectroscopy over a wide range of metalion co...
The first molybdovanadate cluster with a polyarylimido trimetal fragment, [V4Mo3O14(NAr)(3)(mu(2)-NA...