Anhydrous SmCl3 reacts with two equal of Li(1-3-(Bu2C5H3)-Bu-t) to give a complex (1,3-(Bu2C5H3)-Bu-t)(2) Sm(mu -Cl)(2)Li(THF)(2) (C34H58Cl2LiO2Sm, M-r = 726.99), monoclinic, space group P2(1)/n, a = 10.615(2), b = 21.037(4), c = 17.166(3) Angstrom, beta = 93.60(3)degrees, V = 3825.7 (13) Angstrom (3), Z = 4, D-c = 1.262 Mg/m(3), mu = 1.699 mm(-1) and F(000) = 1508, final R = 0.0387 and wR = 0.0741 for 5320 observed[I greater than or equal to2 sigma (I)] reflections. The average Sm - C distance is 2.73 Angstrom. Sm - Cl1 and Sm - Cl2 distances are 2.719 (2) and 2. 697 (2) Angstrom, respectively. Two 1, 3-(Bu2C5H3)-Bu-t-ring centroids and two mu (2)-bridging chloride atoms around Sm atom form a distorted tetrahedron
LaCl3.2LiCl reacts with two equivalents of Bu(t)CpNa in THF to give the complex [(Bu(t)Cp)3LaClLi(TH...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Bis(t-butylcyclopentadienyl)lanthanide chloride (Ln = Nd or Gd) reacts with one equivalent of methyl...
Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 w...
Me4C2(C5H4MgCl)2(THF) (THF = tetrahydrofuran) reacts with anhydrous SmCl3 in THF to give [Me4C2CP2SM...
The structure is mononuclear with samarium bound by two η 5-cyclopentadienyl ligands and two chlorid...
The reaction between LaCl_3 and LiCl in THF at room temperature, with hexane as precipitant and glyc...
[(Me4C2Cp2SmCl.MgCl2.3THF)THF]2 was prepared by the reaction of Me4C2Cp2MgCl2.4THF (Cp=C5H4, THF = t...
Metallation of (HMe2Si)(Me3Si)2CH (1) by LiMe gave the organolithium compound Li(THF)2C(SiMe3)2(SiMe...
The dinuclear complexes of 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolone-4')-1,5-pen...
The title compound, [Sm(C25H35N2)(C14H24Si2)(C4H8O)]·C7H8, was prepared by treatment of anh...
Scandium and lutetium benzyl complexes were prepared. Reaction of [ScCl3(THF)3] with potassium benzy...
Scandium and lutetium benzyl complexes were prepared. Reaction of [ScCl3(THF)(3)] with potassium ben...
Reactions of the β-diketiminate lithium salt L2Li [L2={(2,6-Me2C6H3)NC(Me)}2CH] with anhydrous LnCl3...
The reaction of LnCl3.2LiCl with 1 equiv of MeCpNa in THF gives the complexes [(THF)2Li(mu-Cl)2]2[Me...
LaCl3.2LiCl reacts with two equivalents of Bu(t)CpNa in THF to give the complex [(Bu(t)Cp)3LaClLi(TH...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Bis(t-butylcyclopentadienyl)lanthanide chloride (Ln = Nd or Gd) reacts with one equivalent of methyl...
Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 w...
Me4C2(C5H4MgCl)2(THF) (THF = tetrahydrofuran) reacts with anhydrous SmCl3 in THF to give [Me4C2CP2SM...
The structure is mononuclear with samarium bound by two η 5-cyclopentadienyl ligands and two chlorid...
The reaction between LaCl_3 and LiCl in THF at room temperature, with hexane as precipitant and glyc...
[(Me4C2Cp2SmCl.MgCl2.3THF)THF]2 was prepared by the reaction of Me4C2Cp2MgCl2.4THF (Cp=C5H4, THF = t...
Metallation of (HMe2Si)(Me3Si)2CH (1) by LiMe gave the organolithium compound Li(THF)2C(SiMe3)2(SiMe...
The dinuclear complexes of 1,5-bis(1'-phenyl-3'-methyl-5'-pyrazolone-4')-1,5-pen...
The title compound, [Sm(C25H35N2)(C14H24Si2)(C4H8O)]·C7H8, was prepared by treatment of anh...
Scandium and lutetium benzyl complexes were prepared. Reaction of [ScCl3(THF)3] with potassium benzy...
Scandium and lutetium benzyl complexes were prepared. Reaction of [ScCl3(THF)(3)] with potassium ben...
Reactions of the β-diketiminate lithium salt L2Li [L2={(2,6-Me2C6H3)NC(Me)}2CH] with anhydrous LnCl3...
The reaction of LnCl3.2LiCl with 1 equiv of MeCpNa in THF gives the complexes [(THF)2Li(mu-Cl)2]2[Me...
LaCl3.2LiCl reacts with two equivalents of Bu(t)CpNa in THF to give the complex [(Bu(t)Cp)3LaClLi(TH...
SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C...
Bis(t-butylcyclopentadienyl)lanthanide chloride (Ln = Nd or Gd) reacts with one equivalent of methyl...