Rare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 with two equivalents of C5H9C9H6Li. From mix-solvent of THF and hexane, red color single crystals were obtained. The crystal belongs to a cubic system, space group P2(1)3 with unit cell parameters a= b=c= 1. 754 0(2) nm, alpha=beta=gamma=90degrees, V=5. 396 4(11) nm(3), Z = 4. The ten-coordinated samarium atom is bonded to three cyclopentylindenyl rings and a chlorine atom to form the anionic part of the title complex, ring centroids and the chlorine atom form a tortured tetrahedron around samarium. In the cationic part, lithium atom coordinates to four oxygen atoms of THF molecules to form a normal tetrahedron. The Sm-C(within the same ring) ...
The anionic complexes of the type (ML{sub x})(Me{sub 5}C{sub 5}){sub 2}M'Cl{sub 2}, where M is lithi...
Some lanthanoid(III) perchlorate complexes with the title ligand (dbc-6) have been prepared in methy...
The compounds O(CH2CH2C5H4)(2)Ln(THF)(2) [Ln = Sm(1), Yb(2)] were synthesized by the reduction of O(...
Anhydrous SmCl3 reacts with two equal of Li(1-3-(Bu2C5H3)-Bu-t) to give a complex (1,3-(Bu2C5H3)-Bu-...
(C5H9C5H4)(3)NdBrLi(THF)(4)(1)(C5H9=cyclopentyl) was obtained from the reaction of NdCl3 with C5H9C5...
The reaction between LaCl_3 and LiCl in THF at room temperature, with hexane as precipitant and glyc...
The structure is mononuclear with samarium bound by two η 5-cyclopentadienyl ligands and two chlorid...
By the one-pot reaction of lanthanide trichloride with 2 equivalents of sodium cyclopentadienyl and ...
[(Me4C2Cp2SmCl.MgCl2.3THF)THF]2 was prepared by the reaction of Me4C2Cp2MgCl2.4THF (Cp=C5H4, THF = t...
Reaction of anhydrous ytterbium trichlorides with 2 equiv. of cyclopentylindenyl lithium in THF solu...
Reaction of lanthanoid trichloride with two equivalents of sodium t-butylcyclopentadienide in tetrah...
LnCl3 reacted with K2C8H8 in THF in the ratio 1:1 at room temperature and formed (C8H8)LnCl·nTHF, wh...
Reactions of the β-diketiminate lithium salt L2Li [L2={(2,6-Me2C6H3)NC(Me)}2CH] with anhydrous LnCl3...
The title compound, [Sm(C25H35N2)(C14H24Si2)(C4H8O)]·C7H8, was prepared by treatment of anh...
Me4C2(C5H4MgCl)2(THF) (THF = tetrahydrofuran) reacts with anhydrous SmCl3 in THF to give [Me4C2CP2SM...
The anionic complexes of the type (ML{sub x})(Me{sub 5}C{sub 5}){sub 2}M'Cl{sub 2}, where M is lithi...
Some lanthanoid(III) perchlorate complexes with the title ligand (dbc-6) have been prepared in methy...
The compounds O(CH2CH2C5H4)(2)Ln(THF)(2) [Ln = Sm(1), Yb(2)] were synthesized by the reduction of O(...
Anhydrous SmCl3 reacts with two equal of Li(1-3-(Bu2C5H3)-Bu-t) to give a complex (1,3-(Bu2C5H3)-Bu-...
(C5H9C5H4)(3)NdBrLi(THF)(4)(1)(C5H9=cyclopentyl) was obtained from the reaction of NdCl3 with C5H9C5...
The reaction between LaCl_3 and LiCl in THF at room temperature, with hexane as precipitant and glyc...
The structure is mononuclear with samarium bound by two η 5-cyclopentadienyl ligands and two chlorid...
By the one-pot reaction of lanthanide trichloride with 2 equivalents of sodium cyclopentadienyl and ...
[(Me4C2Cp2SmCl.MgCl2.3THF)THF]2 was prepared by the reaction of Me4C2Cp2MgCl2.4THF (Cp=C5H4, THF = t...
Reaction of anhydrous ytterbium trichlorides with 2 equiv. of cyclopentylindenyl lithium in THF solu...
Reaction of lanthanoid trichloride with two equivalents of sodium t-butylcyclopentadienide in tetrah...
LnCl3 reacted with K2C8H8 in THF in the ratio 1:1 at room temperature and formed (C8H8)LnCl·nTHF, wh...
Reactions of the β-diketiminate lithium salt L2Li [L2={(2,6-Me2C6H3)NC(Me)}2CH] with anhydrous LnCl3...
The title compound, [Sm(C25H35N2)(C14H24Si2)(C4H8O)]·C7H8, was prepared by treatment of anh...
Me4C2(C5H4MgCl)2(THF) (THF = tetrahydrofuran) reacts with anhydrous SmCl3 in THF to give [Me4C2CP2SM...
The anionic complexes of the type (ML{sub x})(Me{sub 5}C{sub 5}){sub 2}M'Cl{sub 2}, where M is lithi...
Some lanthanoid(III) perchlorate complexes with the title ligand (dbc-6) have been prepared in methy...
The compounds O(CH2CH2C5H4)(2)Ln(THF)(2) [Ln = Sm(1), Yb(2)] were synthesized by the reduction of O(...