An imidosamarium(III) cubane has been prepared from the reductive cleavage of azobenzene by a divalent samarium bis (amidinate) complex, indicating that the "spectratoe" bis(amidinate) and the resulting imido ligands help to stabilize the cubane framework. The cubane-type imido cluster is a novel unit in lanthanide chemistry
An unusual chiral lanthanoid cluster has been synthesised and characterised that exhibits a cubane c...
Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...
The syntheses, structures, and magnetic properties are reported for three new lanthanide complexes, ...
A polynuclear samarium imido complex [(L)Sm(4)(mu(3)-NSiMe(3))(4)] (2) featuring a cubane-like clust...
International audienceReaction of 3 equiv of 2,6-diisopropylaniline with Sm[N(SiMe3)2]3 affords the ...
The formation and stabilization of multiple bonds between a lanthanide cation and an anionic p-block...
International audienceThe trivalent rare-earth metal hydrido and imido complexes are of versatile re...
Discrete lanthanide(III) tetranuclear cubane-like clusters seldom occur throughout the Ln<sup>III</...
The oxidation of [Sm(DippForm)(2)(thf)(2)] (1; DippFormH = N,N'-bis(2,6-diisopropylphenyl)forrnamidi...
A comparative study on the stabilizing ability between C5Me4(SiMe3) (Cp' for short) and amidina...
The preparation of a new heterobimetallic samarium(II) formamidinate complex and selected reactions...
Redox transmetallation/protolysis reactions between rare-earth metals, Hg(C6F5)2, and N,N'-bis(4-met...
The treatment of ortho ring-functionalised 1-phenylbutane-1,3-dione ligands bearing nitro (Hnpd, Hnm...
An unprecedentate samarium complex of the molecular composition [{κ3-{(Ph2CH)N=CH}2C4H2N)}{κ3-{(Ph2C...
Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...
An unusual chiral lanthanoid cluster has been synthesised and characterised that exhibits a cubane c...
Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...
The syntheses, structures, and magnetic properties are reported for three new lanthanide complexes, ...
A polynuclear samarium imido complex [(L)Sm(4)(mu(3)-NSiMe(3))(4)] (2) featuring a cubane-like clust...
International audienceReaction of 3 equiv of 2,6-diisopropylaniline with Sm[N(SiMe3)2]3 affords the ...
The formation and stabilization of multiple bonds between a lanthanide cation and an anionic p-block...
International audienceThe trivalent rare-earth metal hydrido and imido complexes are of versatile re...
Discrete lanthanide(III) tetranuclear cubane-like clusters seldom occur throughout the Ln<sup>III</...
The oxidation of [Sm(DippForm)(2)(thf)(2)] (1; DippFormH = N,N'-bis(2,6-diisopropylphenyl)forrnamidi...
A comparative study on the stabilizing ability between C5Me4(SiMe3) (Cp' for short) and amidina...
The preparation of a new heterobimetallic samarium(II) formamidinate complex and selected reactions...
Redox transmetallation/protolysis reactions between rare-earth metals, Hg(C6F5)2, and N,N'-bis(4-met...
The treatment of ortho ring-functionalised 1-phenylbutane-1,3-dione ligands bearing nitro (Hnpd, Hnm...
An unprecedentate samarium complex of the molecular composition [{κ3-{(Ph2CH)N=CH}2C4H2N)}{κ3-{(Ph2C...
Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...
An unusual chiral lanthanoid cluster has been synthesised and characterised that exhibits a cubane c...
Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...
The syntheses, structures, and magnetic properties are reported for three new lanthanide complexes, ...
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