Efficient Electrocatalytic Oxidation of Formic Acid Using Au@Pt Dendrimer-Encapsulated Nanoparticles

We report electrocatalytic oxidation of formic acid using monometallic and bimetallic dendrimer-encapsulated nanoparticles (DENs). The results indicate that the Au₁₄₇@Pt DENs exhibit better electrocatalytic activity and low CO formation. Theoretical calculations attribute the observed activity to the deformation of nanoparticle structure, slow dehydration of formic acid, and weak binding of CO on Au₁₄₇@Pt surface. Subsequent experiments confirmed the theoretical predictions