Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

Yusuke Masuda (1486120)
Maki Hasegawa (842151)
Makoto Yamashita (216887)
Kyoko Nozaki (1616881)
Naoki Ishida (1453135)
Masahiro Murakami (8477)

Publication date

May 2013

DOI

Abstract

The C–C bond of cyclobutanones undergoes oxidative addition to a T-shape rhodium(I) complex possessing a PBP pincer ligand at room temperature. The remarkable propensity of the rhodium complex for oxidative addition is attributed to the highly electron-donating nature of the boron ligand as well as the unsaturation on the rhodium center

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Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

Abstract

Extracted data

Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

Abstract

Extracted data

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