The bifunctional phosphine–abnormal N-heterocyclic carbene ruthenium(II) complex RuBr(OAc)(PPh<sub>3</sub>)(P–aNHC) (<b>1</b>) has been synthesized in high yield by reaction of Ru(OAc)<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub> with a phosphine imidazolium bromide (P–NHC × HBr) and characterized by X-ray diffraction. This compound shows high catalytic activity for the transfer hydrogenation of ketones to alcohols in 2-propanol. Rate and efficiency of <b>1</b> can be enhanced by the addition of ethylenediamine or benzylamine, affording TOFs up to 140 000 h<sup>–1</sup>. Reaction of <b>1</b> with ethylenediamine leads to the Ru carbene/amine complex [Ru(OAc)(PPh<sub>3</sub>)(P–aNHC)(H<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>NH<sub>2</s...
An inorganic-organic hybrid catalyst, Ru(II)Cym@PMOB, was synthesized by anchoring of [Ru(II)Cl2(p-c...
The synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing ...
WOS: 000238053000004Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the...
A mononuclear Ru(II)–N-heterocyclic carbene (NHC) complex [Ru<SUP>II</SUP>(CO)<SUB>2</SUB>(κ<SUP>2</...
Since its discovery by Paul Sabatier, catalytic hydrogenation of unsaturated substrates has become t...
Three RuCI 2(? 6-arene, ? 1-carbene) and two RuCI 2(NHC)(arene) complexes have been prepared by the ...
The ability to acquire and transfer hydrogen catalytically is fundamental to the development of clea...
WOS: 000296049900002Hydrogen-transfer reduction processes are attracting increasing interest from sy...
An alcohol-assisted outer-sphere bifunctional mechanism is proposed for the H<sub>2</sub> hydrogenat...
The reaction of [RuCl 2(p-cymene] 2 with Ag-N-heterocyclic carbene (NHC) complexes yields a series o...
Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in ...
Iridium phosphine abnormal N-heterocyclic carbene complexes in catalytic hydrogen transfer reactions...
WOS: 000232053900009Six ruthenium-N-heterocyclic carbene complexes (2-7) have been prepared and the ...
A series of novel cationic hydroxycyclopentadienyl and methoxycyclopentadienyl N-heterocyclic carben...
A ruthenium (II) N-heterocyclic carbene (NHC) complex was synthesized to investigate ligand dissocia...
An inorganic-organic hybrid catalyst, Ru(II)Cym@PMOB, was synthesized by anchoring of [Ru(II)Cl2(p-c...
The synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing ...
WOS: 000238053000004Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the...
A mononuclear Ru(II)–N-heterocyclic carbene (NHC) complex [Ru<SUP>II</SUP>(CO)<SUB>2</SUB>(κ<SUP>2</...
Since its discovery by Paul Sabatier, catalytic hydrogenation of unsaturated substrates has become t...
Three RuCI 2(? 6-arene, ? 1-carbene) and two RuCI 2(NHC)(arene) complexes have been prepared by the ...
The ability to acquire and transfer hydrogen catalytically is fundamental to the development of clea...
WOS: 000296049900002Hydrogen-transfer reduction processes are attracting increasing interest from sy...
An alcohol-assisted outer-sphere bifunctional mechanism is proposed for the H<sub>2</sub> hydrogenat...
The reaction of [RuCl 2(p-cymene] 2 with Ag-N-heterocyclic carbene (NHC) complexes yields a series o...
Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in ...
Iridium phosphine abnormal N-heterocyclic carbene complexes in catalytic hydrogen transfer reactions...
WOS: 000232053900009Six ruthenium-N-heterocyclic carbene complexes (2-7) have been prepared and the ...
A series of novel cationic hydroxycyclopentadienyl and methoxycyclopentadienyl N-heterocyclic carben...
A ruthenium (II) N-heterocyclic carbene (NHC) complex was synthesized to investigate ligand dissocia...
An inorganic-organic hybrid catalyst, Ru(II)Cym@PMOB, was synthesized by anchoring of [Ru(II)Cl2(p-c...
The synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing ...
WOS: 000238053000004Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the...