One-electron oxidation or reduction of the paramagnetic dinuclear Co(II) complex dmp<sub>2</sub>Nin{Co[N(SiMe<sub>3</sub>)<sub>2</sub>]}<sub>2</sub> (<b>1</b>; dmp<sub>2</sub>Nin<sup>2–</sup> = bis(2,6-dimethylphenyl)nindigo), by fully reversible chemical or electrochemical methods, generates the radical salts [<b>1</b>(OEt<sub>2</sub>)]<sup>+</sup> and [<b>1</b>]<sup>−</sup>, respectively. Full structural and magnetic analyses reveal the locus of the redox changes to be nindigo-based, thus giving rise to ligand-centered radicals sandwiched between two paramagnetic and low-coordinate Co(II) centers. The presence of these sandwiched radicals mediates magnetic coupling between the high-spin (<i>S</i> = <sup>3</sup>/<sub>2</sub>) cobalt...
A dinuclear CoII complex, [Co2(tphz)(tpy)2]n+ (n=4, 3 or 2; tphz: tetrapyridophenazine; tpy: terpyri...
The cobalt macrocycle complex [Co(DIM)Br2]$^+$ (DIM = 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1...
Redox-active organometallic molecules offer a promising avenue for increasing the energy density and...
ABSTRACT: One-electron oxidation or reduction of the paramagnetic dinuclear Co(II) complex dmp2Nin{C...
The reaction of [Co<sup>II</sup>(NO<sub>3</sub>)<sub>2</sub>]·6H<sub>2</sub>O with the nitroxide rad...
A dinuclear CoII complex, [Co2(tphz)(tpy)2]n+ (n=4, 3 or 2; tphz: tetrapyridophenazine; tpy: terpyri...
The electronic structure of the diamagnetic pyridine imine enamide cobalt dinitrogen complex, (<sup>...
The reaction of [Co-II(NO3)(2)]center dot 6H(2)O with the nitroxide radical, 4-dimethyl-2,2-di(2-pyr...
Oxime-based tridentate Schiff base ligands 3-[2-(diethylamino)ethylimino]butan-2-one oxime (HL<sup...
A self-assembled cobalt molecular grid of a pyrazine-bridged bis-tridentate ligand (L<sup>R</sup>), ...
The influence of a redox-active ligand on spin-changing events induced by the coordination of exogen...
Coordination compounds of earth-abundant 3d transition metals are among the most effective catalysts...
International audienceWe report on the synthesis and structural characterization of the cobalt penta...
We have investigated the influence of bound cations on the reduction of cobalt complexes of redox ac...
Triply switchable [Co<sup>II</sup>(dpzca)<sub>2</sub>] shows an abrupt, reversible, and hysteretic s...
A dinuclear CoII complex, [Co2(tphz)(tpy)2]n+ (n=4, 3 or 2; tphz: tetrapyridophenazine; tpy: terpyri...
The cobalt macrocycle complex [Co(DIM)Br2]$^+$ (DIM = 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1...
Redox-active organometallic molecules offer a promising avenue for increasing the energy density and...
ABSTRACT: One-electron oxidation or reduction of the paramagnetic dinuclear Co(II) complex dmp2Nin{C...
The reaction of [Co<sup>II</sup>(NO<sub>3</sub>)<sub>2</sub>]·6H<sub>2</sub>O with the nitroxide rad...
A dinuclear CoII complex, [Co2(tphz)(tpy)2]n+ (n=4, 3 or 2; tphz: tetrapyridophenazine; tpy: terpyri...
The electronic structure of the diamagnetic pyridine imine enamide cobalt dinitrogen complex, (<sup>...
The reaction of [Co-II(NO3)(2)]center dot 6H(2)O with the nitroxide radical, 4-dimethyl-2,2-di(2-pyr...
Oxime-based tridentate Schiff base ligands 3-[2-(diethylamino)ethylimino]butan-2-one oxime (HL<sup...
A self-assembled cobalt molecular grid of a pyrazine-bridged bis-tridentate ligand (L<sup>R</sup>), ...
The influence of a redox-active ligand on spin-changing events induced by the coordination of exogen...
Coordination compounds of earth-abundant 3d transition metals are among the most effective catalysts...
International audienceWe report on the synthesis and structural characterization of the cobalt penta...
We have investigated the influence of bound cations on the reduction of cobalt complexes of redox ac...
Triply switchable [Co<sup>II</sup>(dpzca)<sub>2</sub>] shows an abrupt, reversible, and hysteretic s...
A dinuclear CoII complex, [Co2(tphz)(tpy)2]n+ (n=4, 3 or 2; tphz: tetrapyridophenazine; tpy: terpyri...
The cobalt macrocycle complex [Co(DIM)Br2]$^+$ (DIM = 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1...
Redox-active organometallic molecules offer a promising avenue for increasing the energy density and...