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Ru(II)-Catalyzed <i>ortho</i>-C–H Amination of Arenes and Heteroarenes at Room Temperature

  • Ming Shang (1367952)
  • Shao-Hang Zeng (1897066)
  • Shang-Zheng Sun (1643362)
  • Hui-Xiong Dai (1555198)
  • Jin-Quan Yu (1303500)
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Publication date
October 2013
Icon DOI
10.1021/ol402515s.s001

Abstract

The Ru(II)-catalyzed <i>ortho</i>-C–H amination directed by a weakly coordinating amide auxiliary with <i>O</i>-benzoyl hydroxylamines at room temperature has been achieved. This reaction is compatible with heterocycles including pyrazole, thiophene, benzothiophene, furan, benzofuran, and indole

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