The isothermal crystallization kinetics and morphologies of two centrally branched monodisperse alkanes have been studied and compared with two long n-alkanes, one of equal and one of half, the molecular length of the branched molecules. The two branched alkanes were C96H193.CHR.C94H189 with R being methyl or butyl, respectively, while the long n-alkanes were C194H390 and C98H198. Both branched molecules invariably crystallize once-folded in contrast to both n-alkanes in which molecules are always fully extended in lamellae, demonstrating that branches are excluded and lie in the folds. At high temperatures, both branched systems form scrolls with all folds on the outer convex surface of quasi-cylindrical lamellae. The crystallization range...
SIGLEAvailable from British Library Document Supply Centre- DSC:DXN054077 / BLDSC - British Library ...
In this paper we extend the study of polymorphism and crystallization kinetics of aliphatic polyacet...
We study crystallization in a model system for eicosane (C20) by means of molecular dynamics simulat...
The isothermal crystallization kinetics and morphology have been investigated for a series of dilute...
We synthesized two samples of branched long chain $n$-alkane with methyl and ethyl side groups at th...
A detailed study has been performed on the nucleation, growth and habit modification of n-alkanes an...
Ultralong alkanes (CnH2n+2, n > 150) are generally considered as the most appropriate model for poly...
Higher n-Alkanes (abbr. Cn, n: the number of carbon atoms) in the region that chain folding is found...
Crystallization behavior of hexadecane (C16H34), octadecane (C18H38), eicosane (C20H42), and docosan...
Isothermal and non-isothermal crystallization kinetics of three metallocene-catalysed short-chain-br...
The crystallization behavior and the morphological aspect of the butyl branched alkane C96H193CH(C4H...
The crystallization from dilute solution of two long n-alkanes (C246H494 and C162H326) has been foll...
In this work, we have studied crystallization in short polymer chains using molec-ular dynamics simu...
Polyalkylene dicarboxylates derived from 1,9-nonanediol and mixtures with different ratios of pimeli...
Monodisperse long chain oligomers such as n-alkanes provide excellent model systems for fundamental ...
SIGLEAvailable from British Library Document Supply Centre- DSC:DXN054077 / BLDSC - British Library ...
In this paper we extend the study of polymorphism and crystallization kinetics of aliphatic polyacet...
We study crystallization in a model system for eicosane (C20) by means of molecular dynamics simulat...
The isothermal crystallization kinetics and morphology have been investigated for a series of dilute...
We synthesized two samples of branched long chain $n$-alkane with methyl and ethyl side groups at th...
A detailed study has been performed on the nucleation, growth and habit modification of n-alkanes an...
Ultralong alkanes (CnH2n+2, n > 150) are generally considered as the most appropriate model for poly...
Higher n-Alkanes (abbr. Cn, n: the number of carbon atoms) in the region that chain folding is found...
Crystallization behavior of hexadecane (C16H34), octadecane (C18H38), eicosane (C20H42), and docosan...
Isothermal and non-isothermal crystallization kinetics of three metallocene-catalysed short-chain-br...
The crystallization behavior and the morphological aspect of the butyl branched alkane C96H193CH(C4H...
The crystallization from dilute solution of two long n-alkanes (C246H494 and C162H326) has been foll...
In this work, we have studied crystallization in short polymer chains using molec-ular dynamics simu...
Polyalkylene dicarboxylates derived from 1,9-nonanediol and mixtures with different ratios of pimeli...
Monodisperse long chain oligomers such as n-alkanes provide excellent model systems for fundamental ...
SIGLEAvailable from British Library Document Supply Centre- DSC:DXN054077 / BLDSC - British Library ...
In this paper we extend the study of polymorphism and crystallization kinetics of aliphatic polyacet...
We study crystallization in a model system for eicosane (C20) by means of molecular dynamics simulat...