A new platinum(II)-catalyzed asymmetric ring-opening addition of arylboronic acids to oxabenzonorbornadienes was developed, which afforded the corresponding <i>cis</i>-2-aryl-1,2-dihydronaphthalen-1-ol products in high yields (up to 97%) with moderate to good enantioselectivities (up to 89% ee) under very mild conditions. The effects of various ligands, catalyst loading, bases, solvents, and temperatures on the yield and enantioselectivity of the reaction were also investigated. The cis configuration of product <b>2m</b> was confirmed by X-ray diffraction analysis. A potential mechanism for the present catalytic reaction is proposed
A bis-sulfoxide with a binaphthyl backbone is introduced as a readily available, chiral ligand entit...
The asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds is ...
Iridium-catalyzed asymmetric ring-opening of oxabenzonorbornadienes with N-substituted piperazines w...
A new platinum(II)-catalyzed asymmetric ring-opening addition of arylboronic acids to oxabenzonorbo...
A platinum(II)-catalyzed asymmetric ring opening of oxabenzonorbornadienes with phenols was develop...
A new, versatile, and highly efficient nickel-catalyzed asymmetric ring-opening (ARO) reaction of ox...
A novel iridium-catalyzed asymmetric ring-opening (ARO) reaction of oxabenzonorbornadienes with a va...
Palladium-catalyzed <i>syn</i>-stereocontrolled ring-opening reactions of oxabenzonorbornadienes wit...
[[abstract]]Asymmetric reductive ring opening of oxa- and azabenzonorbornadienes with organic acids ...
Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with various aliphatic an...
The asymmetric ring opening reactions of bicyclic alkenes with boronic acids were accomplished by us...
An efficient enantioselective addition of an array of arylboronic acids to various β-nitrostyrenes c...
Abstract: Rhodium(I)-catalyzed 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compoun...
The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenon...
grantor: University of TorontoOxabenzonorbornadienes were shown to undergo asymmetric ring...
A bis-sulfoxide with a binaphthyl backbone is introduced as a readily available, chiral ligand entit...
The asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds is ...
Iridium-catalyzed asymmetric ring-opening of oxabenzonorbornadienes with N-substituted piperazines w...
A new platinum(II)-catalyzed asymmetric ring-opening addition of arylboronic acids to oxabenzonorbo...
A platinum(II)-catalyzed asymmetric ring opening of oxabenzonorbornadienes with phenols was develop...
A new, versatile, and highly efficient nickel-catalyzed asymmetric ring-opening (ARO) reaction of ox...
A novel iridium-catalyzed asymmetric ring-opening (ARO) reaction of oxabenzonorbornadienes with a va...
Palladium-catalyzed <i>syn</i>-stereocontrolled ring-opening reactions of oxabenzonorbornadienes wit...
[[abstract]]Asymmetric reductive ring opening of oxa- and azabenzonorbornadienes with organic acids ...
Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with various aliphatic an...
The asymmetric ring opening reactions of bicyclic alkenes with boronic acids were accomplished by us...
An efficient enantioselective addition of an array of arylboronic acids to various β-nitrostyrenes c...
Abstract: Rhodium(I)-catalyzed 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compoun...
The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenon...
grantor: University of TorontoOxabenzonorbornadienes were shown to undergo asymmetric ring...
A bis-sulfoxide with a binaphthyl backbone is introduced as a readily available, chiral ligand entit...
The asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds is ...
Iridium-catalyzed asymmetric ring-opening of oxabenzonorbornadienes with N-substituted piperazines w...