A Novel Heterometallic μ<sub>9</sub>‑Boride Cluster: Synthesis and Structural Characterization of [(η<sup>5</sup>‑C<sub>5</sub>Me<sub>5</sub>Rh)<sub>2</sub>{Co<sub>6</sub>(CO)<sub>12</sub>}(μ-H)(BH)B]
- Dipak Kumar Roy (1536370)
- Subrat Kumar Barik (1855765)
- Bijan Mondal (1536382)
- Babu Varghese (1536379)
- Sundargopal Ghosh (1536373)
Publication date
January 2014
DOIAbstract
The preparation, characterization, and electronic structure of the first heterometallic μ<sub>9</sub>-boride cluster [(Cp*Rh)<sub>2</sub>{Co<sub>6</sub>(CO)<sub>12</sub>}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry
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