Syntheses, Structural Variation, and Characterization of a Series of Crystalline Coordination Compounds with 4‑Benzene-1,2,4-triazole: Polymorph, Incomplete Spin Transition, and Single Crystal-to-Single Crystal Transformation
- Xiang Xia Wu (1850341)
- You You Wang (1850338)
- Pan Yang (1447057)
- Yao Yao Xu (1850332)
- Jian Zhong Huo (1850335)
- Bin Ding (1530217)
- Ying Wang (11406)
- XiuGuang Wang (1850329)
DOIAbstract
Based on the 4-substituted 1,2,4-triazole derivate ligand 4-benzene-1,2,4-triazole (L), a series of crystalline coordination complexes varying from mononuclear to trinuclear species, namely, [Zn(L)<sub>2</sub>Br<sub>2</sub>] (<b>1</b>), [Zn(L)<sub>2</sub>Br<sub>2</sub>] (<b>2</b>), [Fe(L)<sub>4</sub>(NCS)<sub>2</sub>]<sub>2</sub> (<b>3</b>), [Fe<sub>2</sub>(μ<sub>2</sub>-L)<sub>3</sub>(L)<sub>2</sub>(NCS)<sub>4</sub>]·CH<sub>3</sub>OH·CH<sub>3</sub>CH<sub>2</sub>OH (<b>4</b>), [Fe<sub>2</sub>(μ<sub>2</sub>-L)<sub>3</sub>(L)<sub>2</sub>(NCS)<sub>4</sub>]·2CH<sub>3</sub>CH<sub>2</sub>OH (<b>5</b>), [Fe<sub>2</sub>(μ<sub>2</sub>-L)<sub>3</sub>(L)<sub>2</sub>(NCS)<sub>4</sub>]·2CH<sub>3</sub>CH<sub>2</sub>OH·1.5H<sub>2</sub>O ...
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