A Family of UO<sub>2</sub><sup>2+</sup>–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species
- Paula M. Cantos (1797109)
- Christopher L. Cahill (1444096)
DOIAbstract
Four new UO<sub>2</sub><sup>2+</sup> compounds were hydrothermally synthesized and incorporate 5-nitro-1,3-benzenedicarboxylic acid (n-bzdc): [(UO<sub>2</sub>)(C<sub>8</sub>N<sub>1</sub>O<sub>6</sub>H<sub>3</sub>)(H<sub>2</sub>O)]·H<sub>2</sub>O (<b>1</b>), [(UO<sub>2</sub>)<sub>2</sub>(C<sub>8</sub>N<sub>1</sub>O<sub>6</sub>H<sub>3</sub>)<sub>2</sub>H<sub>2</sub>O]·TEA (<b>2</b>); [(UO<sub>2</sub>)<sub>2</sub>(OH)(C<sub>8</sub>N<sub>1</sub>O<sub>6</sub>H<sub>3</sub>)<sub>2</sub>]·(TEAH)(H<sub>2</sub>O) (<b>3</b>); [(UO<sub>2</sub>)(C<sub>8</sub>N<sub>1</sub>O<sub>6</sub>H<sub>3</sub>)(C<sub>8</sub>N<sub>1</sub>O<sub>6</sub>H<sub>4</sub>)]·TMAH (<b>4</b>). Compound <b>1</b> consists of pentagonal bipyramidal uranyl monomers bridged vi...
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