Si–H and Si–C Bond Cleavage Reactions of Silane and Phenylsilanes with Mo(PMe<sub>3</sub>)<sub>6</sub>: Silyl, Hypervalent Silyl, Silane, and Disilane Complexes
- Ashley A. Zuzek (1697389)
- Gerard Parkin (1514329)
DOIAbstract
Mo(PMe<sub>3</sub>)<sub>6</sub> cleaves the Si–H bonds of SiH<sub>4</sub>, PhSiH<sub>3</sub>, and Ph<sub>2</sub>SiH<sub>2</sub> to afford a variety of novel silyl, hypervalent silyl, silane, and disilane complexes, as respectively illustrated by Mo(PMe<sub>3</sub>)<sub>4</sub>(SiH<sub>3</sub>)<sub>2</sub>H<sub>2</sub>, Mo(PMe<sub>3</sub>)<sub>4</sub>(κ<sup>2</sup>-<i>H</i><sub>2</sub>-H<sub>2</sub>SiPh<sub>2</sub>H)H, Mo(PMe<sub>3</sub>)<sub>3</sub>(σ-HSiHPh<sub>2</sub>)H<sub>4</sub>, and Mo(PMe<sub>3</sub>)<sub>3</sub>(κ<sup>2</sup>-<i>H</i><sub>2</sub>-H<sub>2</sub>Si<sub>2</sub>Ph<sub>4</sub>)H<sub>2</sub>. Mo(PMe<sub>3</sub>)<sub>4</sub>(κ<sup>2</sup>-<i>H</i><sub>2</sub>-H<sub>2</sub>SiPh<sub>2</sub>H)H and Mo(PMe<sub>3...
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