Anion-Exchange and Anthracene-Encapsulation within Copper(II) and Manganese(II)-Triazole Metal–Organic Confined Space in a Single Crystal-to-Single Crystal Transformation Fashion
- Ju-Yan Liu (537204)
- Qian Wang (32718)
- Li-Jun Zhang (162334)
- Bin Yuan (19897)
- Yao-Yao Xu (1791544)
- Xin Zhang (35492)
- Cong-Ying Zhao (537203)
- Dan Wang (34472)
- Yue Yuan (113839)
- Ying Wang (11406)
- Bin Ding (1530217)
- Xiao-Jun Zhao (537205)
- Min Min Yue (1791547)
DOIAbstract
A new multidentate ligand 1-(9-(1<i>H</i>-1,2,4-triazol-1-yl)anthracen-10-yl)-1<i>H</i>-1,2,4-triazole (tatrz) was designed and synthesized. Using tatrz as a building block, three novel coordination frameworks, namely, {[Cu(tatrz)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>]·(CH<sub>3</sub>OH)·4H<sub>2</sub>O}<sub><i>n</i></sub> (<b>1</b>), {[Cu(tatrz)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](BF<sub>4</sub>)<sub>2</sub>}<sub><i>n</i></sub> (<b>2</b>), and [Mn(tatrz)<sub>2</sub>(SCN)<sub>2</sub>(CH<sub>3</sub>OH)]·2H<sub>2</sub>O (<b>3</b>) can be isolated. Anion-exchange experiment indicates that NO<sub>3</sub><sup>–</sup> anions in the two-dimensional (2D) copper framework of <b>1</b> can be completely exchanged by ClO<sub>4</sub><sup>...