The Al/P-based frustrated Lewis pair (FLP) Mes<sub>2</sub>PC(CHPh)Al(CMe<sub>3</sub>)<sub>2</sub> (<b>1</b>) reacted with boron halides BX<sub>3</sub> (X = F, Cl, Br, I) as an ambiphilic ligand to form complexes (<b>2</b>–<b>5</b>) in which the boron atoms were coordinated to phosphorus and one of the halogen atoms to aluminum. Nonplanar five-membered heterocycles resulted that had five different ring atoms (AlCPBX). The distance of the bridging halogen atoms to the AlCPB plane increased steadily with the radius of the halogen atoms. Only the BF<sub>3</sub> adduct showed a dynamic behavior in solution at room temperature with equivalent <i>tert</i>-butyl or mesityl groups in the NMR spectra, while in other cases, the rigid conformatio...
Körte LA, Blomeyer S, Heidemeyer S, et al. Intramolecular Lewis pairs with two acid sites - reactivi...
The interaction of a Lewis acid with a Lewis base results in the formation of a Lewis acid base addu...
Hydroalumination of aryldialkynylphosphines RP(CC-tBu) 2 (R = Ph, Mes) with equimolar quantities of ...
The Al/P-based frustrated Lewis pair (FLP) Mes<sub>2</sub>PC(CHPh)Al(CMe<sub>3</sub>)<sub>2</s...
The geminal frustrated Lewis pair tBu2PCH2B(Fxyl)2 (1; Fxyl=3,5-(CF3)2C6H3) is accessible in 65 % yi...
This thesis describes the reactivity of geminal phosphorus/boron-based frustrated Lewis pairs in thi...
Combinations of sterically encumbered Lewis acids and bases, now referred to as a frustrated Lewis p...
Combinations of sterically encumbered Lewis acids and Lewis bases are precluded from dative bond for...
The definition of frustrated Lewis pairs has been broadened from combinations of sterically encumber...
While hundreds of papers have been published on frustrated Lewis pairs (FLPs) – the combination of b...
Aluminum–phosphorus-based frustrated Lewis pairs (Al/P FLPs) are valuable reagents for the dipolar a...
Three classes of bifunctional compounds related to frustrated Lewis pair chemistry were studied. The...
Gold(I) and copper(I) imidazolium complexes were synthesized and probed for use as bulky Lewis acids...
A rapid development of metal-free, main group compounds for small molecule activation and as hydroge...
This account describes our work on the use of ambiphilic molecules as catalysts for the reduction of...
Körte LA, Blomeyer S, Heidemeyer S, et al. Intramolecular Lewis pairs with two acid sites - reactivi...
The interaction of a Lewis acid with a Lewis base results in the formation of a Lewis acid base addu...
Hydroalumination of aryldialkynylphosphines RP(CC-tBu) 2 (R = Ph, Mes) with equimolar quantities of ...
The Al/P-based frustrated Lewis pair (FLP) Mes<sub>2</sub>PC(CHPh)Al(CMe<sub>3</sub>)<sub>2</s...
The geminal frustrated Lewis pair tBu2PCH2B(Fxyl)2 (1; Fxyl=3,5-(CF3)2C6H3) is accessible in 65 % yi...
This thesis describes the reactivity of geminal phosphorus/boron-based frustrated Lewis pairs in thi...
Combinations of sterically encumbered Lewis acids and bases, now referred to as a frustrated Lewis p...
Combinations of sterically encumbered Lewis acids and Lewis bases are precluded from dative bond for...
The definition of frustrated Lewis pairs has been broadened from combinations of sterically encumber...
While hundreds of papers have been published on frustrated Lewis pairs (FLPs) – the combination of b...
Aluminum–phosphorus-based frustrated Lewis pairs (Al/P FLPs) are valuable reagents for the dipolar a...
Three classes of bifunctional compounds related to frustrated Lewis pair chemistry were studied. The...
Gold(I) and copper(I) imidazolium complexes were synthesized and probed for use as bulky Lewis acids...
A rapid development of metal-free, main group compounds for small molecule activation and as hydroge...
This account describes our work on the use of ambiphilic molecules as catalysts for the reduction of...
Körte LA, Blomeyer S, Heidemeyer S, et al. Intramolecular Lewis pairs with two acid sites - reactivi...
The interaction of a Lewis acid with a Lewis base results in the formation of a Lewis acid base addu...
Hydroalumination of aryldialkynylphosphines RP(CC-tBu) 2 (R = Ph, Mes) with equimolar quantities of ...