Feedback

Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

  • Toru Amaya (1552171)
  • Yuki Takahashi (1620730)
  • Toshiyuki Moriuchi (1752262)
  • Toshikazu Hirao (1552153)
Open link
Publication date
September 2014
Icon DOI
10.1021/ja5072459.s003

Abstract

Mono- and trinuclear sumanenyl zirconocene complexes Cp­(sumanenyl)­ZrCl<sub>2</sub>, Cp*­(sumanenyl)­ZrCl<sub>2</sub>, and (C<sub>21</sub>H<sub>9</sub>)­[(Cp*)­ZrCl<sub>2</sub>]<sub>3</sub> were successfully synthesized. In the mononuclear complexes, convex binding with disturbed η<sup>5</sup>-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes

Extracted data

We use cookies to provide a better user experience.
Data Protection