Anion-Dependent Assembly of Four Sensitized Near-Infrared Luminescent Heteronuclear Zn<sup>II</sup>–Yb<sup>III</sup> Schiff Base Complexes from a Trinuclear Zn<sup>II</sup> Complex
- Zhi-Peng Zheng (1726105)
- Yan-Jun Ou (1726114)
- Xu-Jia Hong (1726120)
- Lei-Ming Wei (1726108)
- Lin-Tao Wan (1726111)
- Wo-Hua Zhou (1750576)
- Qing-Guang Zhan (1750573)
- Yue-Peng Cai (701205)
DOIAbstract
Four anion-dependent 0D Zn<sup>II</sup>–Yb<sup>III</sup> heterometallic Schiff base complexes, [YbZn<sub>2</sub>L<sub>2</sub>(OAc)<sub>4</sub>]·ClO<sub>4</sub> (<b>2</b>), YbZnL<sub>2</sub>(NO<sub>3</sub>)<sub>3</sub> (<b>3</b>), [(YbL)<sub>2</sub>(H<sub>2</sub>O)Cl(OAc)]<sub>2</sub>·[ZnCl<sub>4</sub>]<sub>2</sub> (<b>4</b>), and YbZnL(OAc)<sub>4</sub> (<b>5</b>), were assembled through central metal substitution or reconstruction from homotrinuclear Zn<sup>II</sup> complex {[(Zn(OAc)(H<sub>2</sub>O)L]<sub>2</sub>Zn}(ClO<sub>4</sub>)<sub>2</sub>·4H<sub>2</sub>O [<b>1</b>; HL = 2-ethoxy-6-[(pyridin-2-ylmethylimino)methyl]phenol] with different Yb<sup>III</sup>X<sub>3</sub> salts [X = ClO<sub>4</sub> (<b>2</b>), NO<sub>3</sub> (<b>3<...
Add to ORKG