A Benzodithiophene-Based Novel Electron Transport Layer for a Highly Efficient Polymer Solar Cell

We designed and synthesized a novel conjugated polyelectrolyte (CPE), poly­{3-[2-[4,8-bis­(2-ethyl-hexyloxy)-6-methyl-1,5-dithia-<i>s</i>-indacen-2-yl]-9-(3-dimethylamino-propyl)-7-methyl-9H-fluoren-9-yl]-propyl}-dimethyl-amine (PBN). We employed PBN as an electron-transporting layer on a ZnO layer and constructed a highly efficient, inverted structure device consisting of a mixture of poly­({4,8-bis­[(2-ethylhexyl)­oxy]­benzo­[1,2-<i>b</i>:4,5-<i>b</i>′]­dithiophene-2,6-diyl}­{3-fluoro-2-[(2-ethylhexyl)­carbonyl]­thieno­[3,4-<i>b</i>]­thiophenediyl}) (PTB7) and PC₇₀BM, achieving a high power conversion of up to 8.6%, constituting a 21.1% improvement over the control device performance (7.1%) prepared without a PBN layer. This result was ascribed to the reduced interfacial resistance and the improved charge transport and collection through the PBN electron transport layer