Bi(OTf)<sub>3</sub>‑Catalyzed Tandem Meyer–Schuster Rearrangement and 1,4-Addition to the Resulting Vinyl Ketone

Noriko Okamoto (159022)
Takuya Sueda (1643527)
Reiko Yanada (1643524)

Publication date

October 2014

DOI

Abstract

Bi(OTf)<sub>3</sub>-catalyzed Meyer–Schuster rearrangement of electron-rich propargyl alcohols, followed by 1,4-addition of the resulting vinyl ketone, proceeded smoothly though Meyer–Schuster rearrangement of primary propargyl alcohols is rare. This tandem reaction can be extended to an intramolecular version, featuring a one-pot dihydroquinolone synthesis

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Bi(OTf)<sub>3</sub>‑Catalyzed Tandem Meyer–Schuster Rearrangement and 1,4-Addition to the Resulting Vinyl Ketone

Abstract

Extracted data

Bi(OTf)<sub>3</sub>‑Catalyzed Tandem Meyer–Schuster Rearrangement and 1,4-Addition to the Resulting Vinyl Ketone

Abstract

Extracted data

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