Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method
- Hongping Wu (1568653)
- Hongwei Yu (3139)
- Qiang Bian (1693981)
- Zhihua Yang (47183)
- Shujuan Han (1705468)
- Shilie Pan (1431682)
Publication date
December 2014
DOIAbstract
By incorporation of the largest-electronegativity F atoms into borate, two novel halogen-containing borates, Li<sub>6</sub>RbB<sub>2</sub>O<sub>6</sub>F and K<sub>3</sub>B<sub>3</sub>O<sub>3</sub>F<sub>6</sub>, have been synthesized. Interestingly, Li<sub>6</sub>RbB<sub>2</sub>O<sub>6</sub>F is the first borate fluoride in alkali-metal borate. Meanwhile, K<sub>3</sub>B<sub>3</sub>O<sub>3</sub>F<sub>6</sub> appears to be the first confirmed alkali-metal fluoroborate crystal grown by a high-temperature solution in air
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