The CO oxidation activity of size-selected Pd<sub>20</sub> clusters deposited on alumina films grown on Re(0001) is shown to depend strongly on the film thickness in the 0 to 10 nm range. For the reaction conditions of these experiments, binding and activation of O<sub>2</sub> is shown to be the limiting process, which can be varied by a factor of 2 by tuning the alumina film thickness, due to effects on both the electronic structure of the alumina film and the morphology of the supported Pd clusters. The alumina films are shown to be doped with Re atoms diffusing from the Re(0001) substrate, leading to a strong dependence of the surface electronic properties on alumina thickness, which in turn, results in the observed thickness-dependent a...
The effect of cluster size, oxidation state, and the support upon the structures and energetics of s...
The interaction between deposited metal clusters and a thin model alumina film grown on NiAl(110) ha...
Metal nanoparticles (MNPs) supported on oxides are used in various catalytic reactions, such as petr...
The size dependence of the electronic structure of Pd clusters deposited on an ordered Al2O3 film on...
International audienceSingle atom catalyst (SAC) is a vivid new area of research in catalysis. Howev...
Cobalt and bimetallic Co-Pd systems are well-known Fischer-Tropsch catalysts. Compared to Co, the bi...
The kinetics of oxidation of ordered arrays of Co nanoparticles (NPs) supported on the ultrathin alu...
CO oxidation reaction was studied over monometallic and bimetallic palladium-platinum catalysts at 2...
First-principles theoretical investigations on the oxidation of Pdn (n=1–7, 10) clusters deposited o...
dissertationThe research presented in this dissertation probes the effects of the metal oxide suppor...
The adsorption of CO on Pd particles supported on a thin alumina film has been studied employing hig...
Catalytic CO oxidation is unveiled on size-selected Pt_(10) clusters deposited on two very different...
A first-principles account of the observed limiting thickness of oxide films formed on aluminum duri...
The interaction of oxygen with Pd particles. vapor deposited onto a thin alumina film grown on a NiA...
Received 18.09.2008 CO oxidation reaction was studied over monometallic and bimetallic palladium–pla...
The effect of cluster size, oxidation state, and the support upon the structures and energetics of s...
The interaction between deposited metal clusters and a thin model alumina film grown on NiAl(110) ha...
Metal nanoparticles (MNPs) supported on oxides are used in various catalytic reactions, such as petr...
The size dependence of the electronic structure of Pd clusters deposited on an ordered Al2O3 film on...
International audienceSingle atom catalyst (SAC) is a vivid new area of research in catalysis. Howev...
Cobalt and bimetallic Co-Pd systems are well-known Fischer-Tropsch catalysts. Compared to Co, the bi...
The kinetics of oxidation of ordered arrays of Co nanoparticles (NPs) supported on the ultrathin alu...
CO oxidation reaction was studied over monometallic and bimetallic palladium-platinum catalysts at 2...
First-principles theoretical investigations on the oxidation of Pdn (n=1–7, 10) clusters deposited o...
dissertationThe research presented in this dissertation probes the effects of the metal oxide suppor...
The adsorption of CO on Pd particles supported on a thin alumina film has been studied employing hig...
Catalytic CO oxidation is unveiled on size-selected Pt_(10) clusters deposited on two very different...
A first-principles account of the observed limiting thickness of oxide films formed on aluminum duri...
The interaction of oxygen with Pd particles. vapor deposited onto a thin alumina film grown on a NiA...
Received 18.09.2008 CO oxidation reaction was studied over monometallic and bimetallic palladium–pla...
The effect of cluster size, oxidation state, and the support upon the structures and energetics of s...
The interaction between deposited metal clusters and a thin model alumina film grown on NiAl(110) ha...
Metal nanoparticles (MNPs) supported on oxides are used in various catalytic reactions, such as petr...