Organic reaction intermediates confined in zeolite cavities are very important for product formation during methanol-to-olefins (MTO) conversion; however, direct evidence is still required to understand the particular function of these intermediates. Herein, for the first time, by careful selection of SAPO molecular sieves with different cavity size but identical 8MR pore openings, the reactivity and role of these intermediates played in olefin generation are verified by isotopic tracing method and theoretical calculations based on the observation of two types of carbenium intermediates, polyMB<sup>+</sup> and polyMCP<sup>+</sup>, under the real MTO reaction conditions. It demonstrates that cavity size controls the molecular size and reacti...
Here, we report that the 8-membered ring pore opening of SAPO-34 zeolite can be significantly modifi...
Catalytic conversion of methanol to light olefins (MTO) over acidic zeolites is currently one of the...
The conversion of methanol to olefins (MTO) over a heterogeneous nanoporous catalyst material is a h...
Organic reaction intermediates confined in zeolite cavities are very important for product formation...
The confinement effect of zeolite cavities on the methanol-to-olefin (MTO) conversion is investigate...
[EN] Small pore zeolites, containing 8-rings as the largest, are widely employed as catalysts in the...
The light olefin product distribution of the methanol-to-olefin (MTO) reaction catalyzed by acid zeo...
Methanol to olefins (MTO) reaction over H-RUB-50 zeolite, an eight-membered ring (8-MR) and cavity-t...
H-MCM-22 zeolite bears three types of pores, supercages, sinusoidal channels, and pockets, and exhib...
Six eight-membered-ring (8MR), microporous materials are synthesized and evaluated as catalysts for ...
Zeolites provide a unique setting for heterogeneous Bronsted acid catalysis, because the effects of ...
The methanol-to-olefins (MTO) reaction produces high value-added light olefins from non-petroleum so...
Methanol can be converted into olefins, aromatics and alkanes over acidic zeolites. The product dist...
In the search for greener and cheaper manufacturing routines for the key chemical compounds ethylene...
The methanol-to-hydrocarbons (MTH) process is a very advantageous way to upgrade methanol to more va...
Here, we report that the 8-membered ring pore opening of SAPO-34 zeolite can be significantly modifi...
Catalytic conversion of methanol to light olefins (MTO) over acidic zeolites is currently one of the...
The conversion of methanol to olefins (MTO) over a heterogeneous nanoporous catalyst material is a h...
Organic reaction intermediates confined in zeolite cavities are very important for product formation...
The confinement effect of zeolite cavities on the methanol-to-olefin (MTO) conversion is investigate...
[EN] Small pore zeolites, containing 8-rings as the largest, are widely employed as catalysts in the...
The light olefin product distribution of the methanol-to-olefin (MTO) reaction catalyzed by acid zeo...
Methanol to olefins (MTO) reaction over H-RUB-50 zeolite, an eight-membered ring (8-MR) and cavity-t...
H-MCM-22 zeolite bears three types of pores, supercages, sinusoidal channels, and pockets, and exhib...
Six eight-membered-ring (8MR), microporous materials are synthesized and evaluated as catalysts for ...
Zeolites provide a unique setting for heterogeneous Bronsted acid catalysis, because the effects of ...
The methanol-to-olefins (MTO) reaction produces high value-added light olefins from non-petroleum so...
Methanol can be converted into olefins, aromatics and alkanes over acidic zeolites. The product dist...
In the search for greener and cheaper manufacturing routines for the key chemical compounds ethylene...
The methanol-to-hydrocarbons (MTH) process is a very advantageous way to upgrade methanol to more va...
Here, we report that the 8-membered ring pore opening of SAPO-34 zeolite can be significantly modifi...
Catalytic conversion of methanol to light olefins (MTO) over acidic zeolites is currently one of the...
The conversion of methanol to olefins (MTO) over a heterogeneous nanoporous catalyst material is a h...