In situ Cobalt–Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution

Remarkable hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalyst has been applied in water splitting, however, utilizing a bifunctional catalyst for simultaneously generating H₂ and O₂ is still a challenging issue, which is crucial for improving the overall efficiency of water electrolysis. Herein, inspired by the superiority of carbon conductivity, the propitious H atom binding energy of metallic cobalt, and better OER activity of cobalt oxide, we synthesized cobalt–cobalt oxide/N-doped carbon hybrids (CoO_<i>x</i>@CN) composed of Co⁰, CoO, Co₃O₄ applied to HER and OER by simple one-pot thermal treatment method. CoO_<i>x</i>@CN exhibited a small onset potential of 85 mV, low charge-transfer resistance (41 Ω), and considerable stability for HER. Electrocatalytic experiments further indicated the better performance of CoO_<i>x</i>@CN for HER can be attributed to the high conductivity of carbon, the synergistic effect of metallic cobalt and cobalt oxide, the stability of carbon-encapsulated Co nanoparticles, and the introduction of electron-rich nitrogen. In addition, when used as catalysts of OER, the CoO_<i>x</i>@CN hybrids required 0.26 V overpotential for a current density of 10 mA cm^–2, which is comparable even superior to many other non-noble metal catalysts. More importantly, an alkaline electrolyzer that approached ∼20 mA cm^–2 at a voltage of 1.55 V was fabricated by applying CoO_<i>x</i>@CN as cathode and anode electrocatalyst, which opened new possibilities for exploring overall water splitting catalysts