Rare Earth Element Concentrations in the Natural Water Reference Materials (NRCC) NASS-5, CASS-4 and SLEW-3

The rare earth element and yttrium concentrations of the NRCC reference materials North Atlantic Surface seawater, NASS-5; Coastal Atlantic Surface Seawater, CASS-4; and the estuarine water, SLEW-3 have been precisely determined by ICP-MS after ca. 1:8 preconcentration following a triple chelation using HDEHP (phosphoric acid 2-ethylhexyl ester -mono and di ester mixture) in heptane, and back extraction in nitric acid. We propose reference values with uncertainties for all naturally occurring lanthanides and yttrium