<div><p>The mixed-metal compounds CpM(CO)<sub>3</sub>(SnPh<sub>3</sub>) (<b>1</b>, M = Mo; <b>2</b>, M = W) are obtained as the only isolable products from the reactions of [CpM(CO)<sub>3</sub>]<sub>2</sub> with PhSSnPh<sub>3</sub>, whereas similar reactions with pymSSnPh<sub>3</sub> (pymS = pyrimidine-2-thiolate) lead to the formation of chelate compounds CpM(CO)<sub>2</sub>(κ<sup>2</sup>-pymS) (<b>3</b>, M = Mo; <b>4</b>, M = W). Separate experiments show that CpM(CO)<sub>3</sub>(SnPh<sub>3</sub>) are precursors of CpM(CO)<sub>2</sub>(κ<sup>2</sup>-pymS). CpM(CO)<sub>3</sub>(SnPh<sub>3</sub>) can also be synthesized in slightly improved yield from the direct reaction between [CpM(CO)<sub>3</sub>]<sub>2</sub> and Ph<sub>3</sub>SnH, while t...
The reaction of Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub> (<b>1</b>) with C<sub>6</sub>H<sub...
The reversible 'ring-opening' reaction of the complex [(OC)3Co(μ-GePh2)(μ-CO)Co(CO)3], (I), with car...
International audiencePhotolysis of [Cp2Mo2(μ-H)(μ-ER)(CO)4] (ER = SMe (1) or SPh (2)) with MeC≡CMe ...
The reaction of [CpMo(CO)(3)](2) (1) and its congener, the triply bonded [CpMo(CO)(2)](2) (2) with 2...
Note:Treatment of CpW(CO)2(PPh3)H, (Cp = 115-cyclopentadienyl) with methyllithium and subsequently w...
Photolysis of a benzene solution containing [(L)Mo(CO)3(C≡CPh)] (L=η5-C5H5 1; η5-C5M...
Photolysis of a benzene solution containing [(L)Mo(CO)3(C≡CPh)] (L=η5-C5H5 1; η5-C5M...
1394-1402The synthesis, characterization and reactivity of a cobalt(II) complex, [(HL1)CoII(PyS)](C...
The well-characterized series of pentaaquoorganochromium(III) complexes, abbreviated (H[subscript]2O...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
The reaction of the unsaturated cluster [(mu -H)Os-3(CO)(8) {Ph2PCH2P(Ph)C6H4}] 2 with C2H5SH, CH3CH...
Cp'Mn(CO)3 (Cp'=h5-C5H4-CH 3) reacts with P(C6H5)2H in THF to give Cp'(CO)2MnPPh2H (Ph = Phenyl) (1)...
The reaction of Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub> (<b>1</b>) with C<sub>6</sub>H<sub...
The reaction of Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub> (<b>1</b>) with C<sub>6</sub>H<sub...
The reversible 'ring-opening' reaction of the complex [(OC)3Co(μ-GePh2)(μ-CO)Co(CO)3], (I), with car...
International audiencePhotolysis of [Cp2Mo2(μ-H)(μ-ER)(CO)4] (ER = SMe (1) or SPh (2)) with MeC≡CMe ...
The reaction of [CpMo(CO)(3)](2) (1) and its congener, the triply bonded [CpMo(CO)(2)](2) (2) with 2...
Note:Treatment of CpW(CO)2(PPh3)H, (Cp = 115-cyclopentadienyl) with methyllithium and subsequently w...
Photolysis of a benzene solution containing [(L)Mo(CO)3(C≡CPh)] (L=η5-C5H5 1; η5-C5M...
Photolysis of a benzene solution containing [(L)Mo(CO)3(C≡CPh)] (L=η5-C5H5 1; η5-C5M...
1394-1402The synthesis, characterization and reactivity of a cobalt(II) complex, [(HL1)CoII(PyS)](C...
The well-characterized series of pentaaquoorganochromium(III) complexes, abbreviated (H[subscript]2O...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
International audienceThe new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2...
The reaction of the unsaturated cluster [(mu -H)Os-3(CO)(8) {Ph2PCH2P(Ph)C6H4}] 2 with C2H5SH, CH3CH...
Cp'Mn(CO)3 (Cp'=h5-C5H4-CH 3) reacts with P(C6H5)2H in THF to give Cp'(CO)2MnPPh2H (Ph = Phenyl) (1)...
The reaction of Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub> (<b>1</b>) with C<sub>6</sub>H<sub...
The reaction of Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub> (<b>1</b>) with C<sub>6</sub>H<sub...
The reversible 'ring-opening' reaction of the complex [(OC)3Co(μ-GePh2)(μ-CO)Co(CO)3], (I), with car...
International audiencePhotolysis of [Cp2Mo2(μ-H)(μ-ER)(CO)4] (ER = SMe (1) or SPh (2)) with MeC≡CMe ...