Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand
- Jamie Hicks (1589182)
- Cameron Jones (1563892)
Publication date
June 2015
DOIAbstract
A series of low-coordinate, high-spin, mono- and dinuclear cobalt(I) complexes bearing an extremely bulky amide (L″ = N(Ar*)(SiPh<sub>3</sub>); Ar* = C<sub>6</sub>H<sub>2</sub>{C(H)Ph<sub>2</sub>}<sub>2</sub>Me-2,6,4) ligand have been synthesized and characterized. These include the first example of a neutral two-coordinate cobalt(I) complex, [L″Co(IPriMe)] (IPriMe = :C{N(Pr<sup><i>i</i></sup>)C(Me)}<sub>2</sub>), which has a near-linear cobalt coordination geometry
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