Sequential treatment at low temperatures of Cp*W(NO)Cl<sub>2</sub> in THF with 1 equiv of a binary magnesium allyl reagent, followed by an excess of LiBH<sub>4</sub>, affords three new Cp*W(NO)(H)(η<sup>3</sup>-allyl) complexes, namely, Cp*W(NO)(H)(η<sup>3</sup>-CH<sub>2</sub>CHCMe<sub>2</sub>) (<b>1</b>), Cp*W(NO)(H)(η<sup>3</sup>-CH<sub>2</sub>CHCHPh) (<b>2</b>), and Cp*W(NO)(H)(η<sup>3</sup>-CH<sub>2</sub>CHCHMe) (<b>3</b>). Complexes <b>1</b>–<b>3</b> are isolable as air-stable, analytically pure yellow solids in good to moderate yields by chromatography or fractional crystallization. In solutions, complex <b>1</b> exists as two coordination isomers in an 83:17 ratio differing with respect to the <i>endo</i>/<i>exo</i> ori...
Reaction of Na[η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub><sup><i>i</i></sup>Pr] with W(CO)<sub>6</su...
Synthetic protocols for a pyrrolide-centered ONO<sup>3–</sup> trianionic pincer-type ligand are pres...
Cp*W(NO)(H)(η³-CH₂CHCHMe) (2.1) [Cp* = η⁵-C₅Me₅] effects the formation of unsymmetrical ketones from...
Sequential treatment at low temperatures of Cp*W(NO)Cl<sub>2</sub> in THF with 1 equiv of a binary...
The thermal properties of Cp*W(NO)(H)(η<sup>3</sup>-CH<sub>2</sub>CHCMe<sub>2</sub>) (<b>1</b>), ...
The thermal properties of Cp*W(NO)(H)(η3-CH2CHCMe2) (1), Cp*W(NO)(H)(η3-CH2CHCHPh) (2), and Cp*W(NO)...
The η⁵-C₅H₄iPr ligand imparts unprecedented effects on the physical and chemical properties of (η⁵-C...
The complexes trans-Cp*W(NO)(CH2CMe3)(H)(L) (Cp* = η5-C5Me5) result from the treatment of Cp*W(NO)(C...
Thermolysis of Cp*W(NO)(CH₂CMe₃)₂ (2.1) in halo, methoxy, or phenylethynyl-substituted benzenes lead...
The complexes <i>trans</i>-Cp*W(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(H)(L) (Cp* = η<sup>5</sup>-C<...
In an effort to study the β-H abstraction/1,3-addition mechanism for CH bond activation, the synthes...
The novel family of Cp*W(NO)(H)(η³-allyl) complexes has been synthesized and characterized. Upon the...
Thermolyses of 18e Cp*W(NO)(η<sup>3</sup>-allyl)(CH<sub>2</sub>CMe<sub>3</sub>) compounds (Cp* = ...
The thermolysis of Cp*W(NO)(Npt)(η<sup>3</sup>-CH<sub>2</sub>CHCHSiMe<sub>3</sub>) (<b>1</b>; Cp*...
The reactions of (ɳ⁵-C₅R₅)M(NO)(CO)₂ (R = H, Me; M = Mo, W) with PCl₅ result in the formation of the...
Reaction of Na[η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub><sup><i>i</i></sup>Pr] with W(CO)<sub>6</su...
Synthetic protocols for a pyrrolide-centered ONO<sup>3–</sup> trianionic pincer-type ligand are pres...
Cp*W(NO)(H)(η³-CH₂CHCHMe) (2.1) [Cp* = η⁵-C₅Me₅] effects the formation of unsymmetrical ketones from...
Sequential treatment at low temperatures of Cp*W(NO)Cl<sub>2</sub> in THF with 1 equiv of a binary...
The thermal properties of Cp*W(NO)(H)(η<sup>3</sup>-CH<sub>2</sub>CHCMe<sub>2</sub>) (<b>1</b>), ...
The thermal properties of Cp*W(NO)(H)(η3-CH2CHCMe2) (1), Cp*W(NO)(H)(η3-CH2CHCHPh) (2), and Cp*W(NO)...
The η⁵-C₅H₄iPr ligand imparts unprecedented effects on the physical and chemical properties of (η⁵-C...
The complexes trans-Cp*W(NO)(CH2CMe3)(H)(L) (Cp* = η5-C5Me5) result from the treatment of Cp*W(NO)(C...
Thermolysis of Cp*W(NO)(CH₂CMe₃)₂ (2.1) in halo, methoxy, or phenylethynyl-substituted benzenes lead...
The complexes <i>trans</i>-Cp*W(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(H)(L) (Cp* = η<sup>5</sup>-C<...
In an effort to study the β-H abstraction/1,3-addition mechanism for CH bond activation, the synthes...
The novel family of Cp*W(NO)(H)(η³-allyl) complexes has been synthesized and characterized. Upon the...
Thermolyses of 18e Cp*W(NO)(η<sup>3</sup>-allyl)(CH<sub>2</sub>CMe<sub>3</sub>) compounds (Cp* = ...
The thermolysis of Cp*W(NO)(Npt)(η<sup>3</sup>-CH<sub>2</sub>CHCHSiMe<sub>3</sub>) (<b>1</b>; Cp*...
The reactions of (ɳ⁵-C₅R₅)M(NO)(CO)₂ (R = H, Me; M = Mo, W) with PCl₅ result in the formation of the...
Reaction of Na[η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub><sup><i>i</i></sup>Pr] with W(CO)<sub>6</su...
Synthetic protocols for a pyrrolide-centered ONO<sup>3–</sup> trianionic pincer-type ligand are pres...
Cp*W(NO)(H)(η³-CH₂CHCHMe) (2.1) [Cp* = η⁵-C₅Me₅] effects the formation of unsymmetrical ketones from...