Carbene-Induced Intra- vs Intermolecular Transfer-Fluoromethylation of Aryl Fluoromethylthio Compounds under Rhodium Catalysis
- Ibrayim Saidalimu (1554556)
- Etsuko Tokunaga (1479160)
- Norio Shibata (1479169)
Publication date
August 2015
DOIAbstract
The intra- vs intermolecular transfer-fluoromethylation of aryl fluoromethylthio compounds is proposed. Finely designed ArSCF<sub>3</sub> (<b>1a</b>) nicely releases its trifluoromethyl (CF<sub>3</sub>) group intermolecularly under rhodium catalysis, whereas a difluoromethylated analogue, ArSCF<sub>2</sub>H compound <b>1b</b> shows intramolecular reaction
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