Chemical Synthesis and Characterization of γ‑Co₂NiGa Nanoparticles with a Very High Curie Temperature

We report the first study on the chemical preparation, structural characterization, and magnetic properties of Co₂NiGa nanoparticles (NPs) of a single γ-phase (γ-Co₂NiGa). The γ-Co₂NiGa NPs were prepared by impregnation in colloidal silica followed by high temperature annealing under hydrogen atmosphere. The crystal structure of tetragonal γ-Co₂NiGa was confirmed by selected area electron and X-ray diffraction studies. Energy-dispersive X-ray spectroscopy mapping and X-ray absorption near edge structure data provided evidence for the successful preparation of the intermetallic NPs and the absence of Co, Ni, Co–Ni, or metal-containing impurity phases. Extended X-ray absorption fine structure spectroscopy data confirmed the formation of the γ-Co₂NiGa phase by examining the atomic environments surrounding Co, Ni, and Ga. The Co₂NiGa NPs are ferromagnetic with a high saturation magnetization, which is consistent with the theoretical model. γ-Co₂NiGa NPs exhibit a very high Curie temperature (≈1139 K), which make them promising candidates for high temperature magnetically activated nanoscale devices