Hauser–Heck: Efficient Synthesis of γ‑Aryl-β-ketoesters en Route to Substituted Naphthalenes

γ-Aryl-β-ketoesters can be prepared in one step from aryl bromides and bis­(trimethylsilyl) enol ethers using catalytic amounts of Pd­(dba)₂/<i>t-</i>Bu₃P and stoichiometric amounts of Bu₃SnF. The wide range of γ-(hetero)­aryl-β-ketoesters that can be obtained illustrate the scope and limitations of this novel Hauser–Heck combination. γ-Aryl-β-ketoesters with a 1,3-dioxane acetal in the <i>ortho</i> position can easily be transformed into the hydroxy naphthoate in very good yield. Aqueous formic acid at 65 °C provides optimal conditions for this deprotective aromatization