Controlling the assembly of soft and deformable molecular aggregates into mesoscale structures is essential for understanding and developing a broad range of processes including rare earth extraction and cleaning of water, as well as for developing materials with unique properties. By combined synchrotron small- and wide-angle X-ray scattering with large-scale atomistic molecular dynamics simulations we analyze here a metalloamphiphile–oil solution that organizes on multiple length scales. The molecules associate into aggregates, and aggregates flocculate into meso-ordered phases. Our study demonstrates that dipolar interactions, centered on the amphiphile headgroup, bridge ionic aggregate cores and drive aggregate flocculation. By identify...
In this article we investigate the complexity of the molecular architectures of liquid crystals base...
We describe herein the hierarchical self-assembly of discrete supramolecular metallacycles into orde...
Aggregation of stiff polyelectrolytes in solution and angle- and distance-dependent potential of mea...
We report atomistic molecular dynamics (MD) simulations of model ionomers with precise spacing betwe...
Frank-Kasper (F-K) and quasicrystal phases were originally identified in metal alloys and only spora...
Although the self-assembly of amphiphiles is well-studied in aqueous solutions, much less is underst...
There is an ever-increasing body of evidence that metallic complexes involving amphiliphic ligands d...
Spontaneous self-assembly in molecular systems is a fundamental route to both biological and enginee...
Short- and long-range correlations between solutes in solvents can influence the macroscopic chemist...
Self-assembly in natural and synthetic molecular systems can create complex aggregates or materials ...
Self-assembled diphenylalanine (FF) nanostructures have recently been demonstrated to be interesting...
Short- and long-range correlations between solutes in solvents can influence the macroscopic chemist...
A mechanistic understanding of metal–organic framework (MOF) synthesis and scale-up remains underexp...
Extensive research on hydrogen bonds (H-bonds) have illustrated their critical role in various biolo...
Self-assembly of nanocrystals into functional materials requires precise control over nanoparticle i...
In this article we investigate the complexity of the molecular architectures of liquid crystals base...
We describe herein the hierarchical self-assembly of discrete supramolecular metallacycles into orde...
Aggregation of stiff polyelectrolytes in solution and angle- and distance-dependent potential of mea...
We report atomistic molecular dynamics (MD) simulations of model ionomers with precise spacing betwe...
Frank-Kasper (F-K) and quasicrystal phases were originally identified in metal alloys and only spora...
Although the self-assembly of amphiphiles is well-studied in aqueous solutions, much less is underst...
There is an ever-increasing body of evidence that metallic complexes involving amphiliphic ligands d...
Spontaneous self-assembly in molecular systems is a fundamental route to both biological and enginee...
Short- and long-range correlations between solutes in solvents can influence the macroscopic chemist...
Self-assembly in natural and synthetic molecular systems can create complex aggregates or materials ...
Self-assembled diphenylalanine (FF) nanostructures have recently been demonstrated to be interesting...
Short- and long-range correlations between solutes in solvents can influence the macroscopic chemist...
A mechanistic understanding of metal–organic framework (MOF) synthesis and scale-up remains underexp...
Extensive research on hydrogen bonds (H-bonds) have illustrated their critical role in various biolo...
Self-assembly of nanocrystals into functional materials requires precise control over nanoparticle i...
In this article we investigate the complexity of the molecular architectures of liquid crystals base...
We describe herein the hierarchical self-assembly of discrete supramolecular metallacycles into orde...
Aggregation of stiff polyelectrolytes in solution and angle- and distance-dependent potential of mea...