Copper-Catalyzed Cross-Coupling of Allylboronic Acids with α‑Diazoketones

Arindam Das (1327752)
Dong Wang (73290)
Marie-Charlotte Belhomme (1366515)
Kálmán J. Szabó (1275192)

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Publication date

December 2015

DOI

10.1021/acs.orglett.5b02285.s001

ISSN

1523-7060

Citation count (estimate)

Abstract

Copper-catalyzed cross-coupling of substituted allylboronic acids with α-diazoketones was studied. This allylation reaction is highly regioselective, providing the branched allylic product. The process involves creation of a new C(sp<sup>3</sup>)–C(sp<sup>3</sup>) bond by retaining the keto functional group of the α-diazoketone precursor

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Copper-Catalyzed Cross-Coupling of Allylboronic Acids with α‑Diazoketones

Abstract

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Copper-Catalyzed Cross-Coupling of Allylboronic Acids with α‑Diazoketones

Abstract

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