Aryldihydroborane Coordination to Iridium and Osmium Hydrido Complexes
- Nicole Arnold (1438777)
- Silvia Mozo (1450837)
- Ursula Paul (1450831)
- Udo Radius (1450834)
- Holger Braunschweig (1370640)
DOIAbstract
A series of iridium dihydroborate complexes [(<sup>t</sup>BuPOCOP)IrH(κ<sup>2</sup>-H<sub>2</sub>BHR)] (<sup>t</sup>BuPOCOP = κ<sup>3</sup>-C<sub>6</sub>H<sub>3</sub>-1,3-[OP<sup>t</sup>Bu<sub>2</sub>]<sub>2</sub>; R = Mes = 2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>; R = Dur = 2,3,5,6-Me<sub>4</sub>C<sub>6</sub>H) and [LIrH(κ<sup>2</sup>-H<sub>2</sub>BHDur)] (L = <sup>t</sup>BuPCP = κ<sup>3</sup>-C<sub>6</sub>H<sub>3</sub>-1,3-[CH<sub>2</sub>P<sup>t</sup>Bu<sub>2</sub>]<sub>2</sub>, L = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>) and an osmium dihydroborate compound [OsH(κ<sup>2</sup>-H<sub>2</sub>BHDur)(CO)(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub>] have been prepared by using two different synthetic strategies. The first approach...
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