The novel P-arylation of dialkyl phosphites and secondary phosphine oxides with arynes has been achieved. The reactions produce dialkyl arylphosphonates in 71–99% yield and tertiary phosphine oxides in 68–92% yield under mild conditions
International audienceAlkynylphosphines or their borane complexes are available either through C-P b...
The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and a...
Two new general synthetic routes to phosphines were developed. The first method described directly c...
Synthesis of organo-phosphorus compounds and their application in organic synthesis and life science...
The insertion of arynes into P–O bonds for the preparation of <i>o</i>-hydroxy-substituted arylphosp...
The synthesis of tertiary phosphine oxides from phosphonates was achieved reliably and in good to ex...
Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of s...
Electrochemical oxidation of trialkyl phosphites in the presence of aromatic hydrocarbons at glass-c...
© 2016 Bentham Science Publishers.Conjugate addition of dialkyl phosphites and ethyl phenylphosphina...
Arynes are highly reactive intermediates, which are utilized for the electrophilic arylation of vari...
A diphosphination of arynes with diphosphines has been developed. The reaction of stable aryne precu...
Arynes are highly reactive intermediates, which are utilized for the electrophilic arylation of vari...
We report a diversification strategy that enables the direct substituent exchange of tertiary phosph...
Treatment of a dialkyl phosphite with triphenylphosphine and diisopropyl azodicarboxylate in toluene...
A scalable synthetic route to both primary arylphosphines ArPH2 and aryldichlorophosphines ArPCl2 is...
International audienceAlkynylphosphines or their borane complexes are available either through C-P b...
The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and a...
Two new general synthetic routes to phosphines were developed. The first method described directly c...
Synthesis of organo-phosphorus compounds and their application in organic synthesis and life science...
The insertion of arynes into P–O bonds for the preparation of <i>o</i>-hydroxy-substituted arylphosp...
The synthesis of tertiary phosphine oxides from phosphonates was achieved reliably and in good to ex...
Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of s...
Electrochemical oxidation of trialkyl phosphites in the presence of aromatic hydrocarbons at glass-c...
© 2016 Bentham Science Publishers.Conjugate addition of dialkyl phosphites and ethyl phenylphosphina...
Arynes are highly reactive intermediates, which are utilized for the electrophilic arylation of vari...
A diphosphination of arynes with diphosphines has been developed. The reaction of stable aryne precu...
Arynes are highly reactive intermediates, which are utilized for the electrophilic arylation of vari...
We report a diversification strategy that enables the direct substituent exchange of tertiary phosph...
Treatment of a dialkyl phosphite with triphenylphosphine and diisopropyl azodicarboxylate in toluene...
A scalable synthetic route to both primary arylphosphines ArPH2 and aryldichlorophosphines ArPCl2 is...
International audienceAlkynylphosphines or their borane complexes are available either through C-P b...
The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and a...
Two new general synthetic routes to phosphines were developed. The first method described directly c...
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