Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

Chunliang Zhao (1433977)
Li-Chuan Liu (1433980)
Jing Wang (1228470)
Chenran Jiang (1433974)
Qing-Wei Zhang (1433971)
Wei He (131453)

Publication date

January 2016

DOI

10.1021/acs.orglett.5b03518.s001

Abstract

Herein we report a Rh(I)-catalyzed two carbon insertion into C–C bonds of benzocyclobutenols by employing symmetrical and unsymmetrical allenes. This reaction provides rapid access to alkylidene tetralins bearing two adjacent stereogenic centers in good yields and diasteroselectivities

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Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

Abstract

Extracted data

Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

Abstract

Extracted data

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