The compounds 4,4′-bis[(<i>E</i>)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocenyl [(Fcv)<sub>2</sub>bpy], octamethylferrocenyl [(Me<sub>8</sub>Fcv)<sub>2</sub>bpy] or 4-(diphenylamino)phenyl [(Dapv)<sub>2</sub>bpy]} are used to prepare eight new complexes with Zn<sup>II</sup>Cl<sub>2</sub>, Zn<sup>II</sup>(OAc)<sub>2</sub>, or <i>fac</i>-Re<sup>I</sup>Cl(CO)<sub>3</sub> centers. The recently reported complex <i>fac</i>-Re<sup>I</sup>Cl(CO)<sub>3</sub>[(Dapv)<sub>2</sub>bpy] (Horvath, R. et al. Inorg. Chem. 2013, 52, 1304) is also studied. Electronic absorption spectra show intense d → π* metal-to-ligand charge-transfer (MLCT) and π → π* intraligand charge-transfer (ILCT) absorption bands, the relative energies of which correlate logically wit...
In this article, we contrast the optical properties of dipolar chromophores having 4-(dimethylamino)...
Nonlinear Optics deals with the modification of material properties under the influence of intense l...
A series of five new dipolar cations has been synthesized with ferrocenyl (Fc) electron donor groups...
The compounds 4,4′-bis[(<i>E</i>)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocenyl [(Fcv)<sub>2</sub>bpy],...
The compounds 4,4′-bis[(E)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocenyl [(Fcv)_2bpy], octamethylferroce...
© 2015 American Chemical Society. The compounds 4,4′-bis[(E)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocen...
The compounds 4,4′-dicyano-2,2′-bipyridyl (dcbpy), 4,4′-bis(4-cyanophenyl)-2,2′-bipyridyl (bcpbpy),...
© 2016 American Chemical Society. The compounds 4,4′-dicyano-2,2′-bipyridyl (dcbpy), 4,4′-bis(4-cyan...
Three new dipolar cations have been synthesised, containing ferrocenyl (Fc) electron donor groups at...
A series of substituted ferrocenyl compounds where one of the cyclopentadienyl rings is linked to an...
The complexes trans-[Ru(CC-4-C6H4F)X(dppe) 2] [X = Cl (1), CCPh (2), CC-4-C6H4NO 2 (3)], trans-[Ru{C...
The coherent, monochromatic and intense light of a laser opened the way to research in nonlinear opt...
The coherent, monochromatic and intense light of a laser opened the way to research in nonlinear opt...
International audienceThe molecular engineering of organometallic complexes has recently attracted r...
The authors report an ab initio study of 2nd-order nonlinear optical (NLO) properties and absorption...
In this article, we contrast the optical properties of dipolar chromophores having 4-(dimethylamino)...
Nonlinear Optics deals with the modification of material properties under the influence of intense l...
A series of five new dipolar cations has been synthesized with ferrocenyl (Fc) electron donor groups...
The compounds 4,4′-bis[(<i>E</i>)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocenyl [(Fcv)<sub>2</sub>bpy],...
The compounds 4,4′-bis[(E)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocenyl [(Fcv)_2bpy], octamethylferroce...
© 2015 American Chemical Society. The compounds 4,4′-bis[(E)-2-R-vinyl]-2,2′-bipyridyl {R = ferrocen...
The compounds 4,4′-dicyano-2,2′-bipyridyl (dcbpy), 4,4′-bis(4-cyanophenyl)-2,2′-bipyridyl (bcpbpy),...
© 2016 American Chemical Society. The compounds 4,4′-dicyano-2,2′-bipyridyl (dcbpy), 4,4′-bis(4-cyan...
Three new dipolar cations have been synthesised, containing ferrocenyl (Fc) electron donor groups at...
A series of substituted ferrocenyl compounds where one of the cyclopentadienyl rings is linked to an...
The complexes trans-[Ru(CC-4-C6H4F)X(dppe) 2] [X = Cl (1), CCPh (2), CC-4-C6H4NO 2 (3)], trans-[Ru{C...
The coherent, monochromatic and intense light of a laser opened the way to research in nonlinear opt...
The coherent, monochromatic and intense light of a laser opened the way to research in nonlinear opt...
International audienceThe molecular engineering of organometallic complexes has recently attracted r...
The authors report an ab initio study of 2nd-order nonlinear optical (NLO) properties and absorption...
In this article, we contrast the optical properties of dipolar chromophores having 4-(dimethylamino)...
Nonlinear Optics deals with the modification of material properties under the influence of intense l...
A series of five new dipolar cations has been synthesized with ferrocenyl (Fc) electron donor groups...