Zn<sub>7</sub>O<sub>2</sub>(RCOO)<sub>10</sub> Clusters and Nitro Aromatic Linkers in a Porous Metal–Organic Framework
- Simon S. Iremonger (1970314)
- Ramanathan Vaidhyanathan (1970317)
- Roger K. Mah (1941409)
- George K. H. Shimizu (1578769)
Publication date
February 2016
DOIAbstract
A new metal–organic framework, CALF-22 comprising Zn<sub>7</sub>O<sub>2</sub>(COO)<sub>10</sub> secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N<sub>2</sub>, H<sub>2</sub>, CO<sub>2</sub>, and CH<sub>4</sub> are studied, and CALF-22 has a surface area in excess of 1000 m<sup>2</sup>/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied
Add to ORKG